• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利:CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法,用中文像聊天一样搜索,搜遍4000万医学文献。AI智能推荐,让科研检索更轻松。

立即免费搜索

文件翻译

保留排版,准确专业,支持PDF/Word/PPT等文件格式,支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述,25分钟生成高质量综述,智能提取关键信息,辅助科研写作。

立即免费体验

Highly selective metal catalysts for intermolecular carbenoid insertion into primary C-H bonds and enantioselective C-C bond formation.

作者信息

Thu Hung-Yat, Tong Glenna So-Ming, Huang Jie-Sheng, Chan Sharon Lai-Fung, Deng Qing-Hai, Che Chi-Ming

机构信息

Department of Chemistry and Open Laboratory of Chemical Biology of the Institute of Molecular Technology for Drug Discovery and Synthesis, The University of Hong Kong, Pokfulam Road, Hong Kong.

出版信息

Angew Chem Int Ed Engl. 2008;47(50):9747-51. doi: 10.1002/anie.200803157.

DOI:10.1002/anie.200803157
PMID:18855950
Abstract
摘要

相似文献

1
Highly selective metal catalysts for intermolecular carbenoid insertion into primary C-H bonds and enantioselective C-C bond formation.用于分子间类卡宾插入到伯碳氢键中以及对映选择性碳-碳键形成的高选择性金属催化剂。
Angew Chem Int Ed Engl. 2008;47(50):9747-51. doi: 10.1002/anie.200803157.
2
Rhodium-mediated activation of an alkane-type C-H bond.铑介导的烷烃型 C-H 键的活化。
Chem Commun (Camb). 2010 Jan 14;46(2):315-7. doi: 10.1039/b918660c. Epub 2009 Nov 26.
3
De novo synthesis of Troc-protected amines: intermolecular rhodium-catalyzed C-H amination with N-tosyloxycarbamates.Troc保护胺的从头合成:铑催化的与N-甲苯磺酰氧基氨基甲酸酯的分子间C-H胺化反应
Org Lett. 2007 Feb 15;9(4):639-42. doi: 10.1021/ol062953t. Epub 2007 Jan 23.
4
N-tosyloxycarbamates as reagents in rhodium-catalyzed C-H amination reactions.N-对甲苯磺酰氧基氨基甲酸酯作为铑催化的C-H胺化反应中的试剂。
Chemistry. 2008;14(20):6222-30. doi: 10.1002/chem.200702027.
5
Guiding principles for site selective and stereoselective intermolecular C-H functionalization by donor/acceptor rhodium carbenes.通过给体/受体铑卡宾实现位点选择性和立体选择性的分子间 C-H 功能化的指导原则。
Chem Soc Rev. 2011 Apr;40(4):1857-69. doi: 10.1039/c0cs00217h. Epub 2011 Mar 1.
6
Formal aromatic C-H insertion for stereoselective isoquinolinone synthesis and studies on mechanistic insights into the C-C bond formation.通过形式芳香 C-H 插入反应进行立体选择性异喹啉酮合成,并对 C-C 键形成的机理进行研究。
J Org Chem. 2009 Aug 21;74(16):6231-6. doi: 10.1021/jo9011255.
7
Origins of the selectivity for borylation of primary over secondary C-H bonds catalyzed by Cp*-rhodium complexes.Cp*-铑配合物催化的伯 C-H 键与仲 C-H 键硼化选择性的起源。
J Am Chem Soc. 2010 Mar 10;132(9):3078-91. doi: 10.1021/ja909453g.
8
Highly selective rhodium catalyzed domino C-H activation/cyclizations.高度选择性铑催化的多米诺C-H活化/环化反应
Chimia (Aarau). 2011;65(4):271-3.
9
Easy access to isoquinolines and tetrahydroquinolines from ketoximes and alkynes via rhodium-catalyzed C-H bond activation.通过铑催化的 C-H 键活化,从酮肟和炔烃中轻松获得异喹啉和四氢喹啉。
J Org Chem. 2009 Dec 18;74(24):9359-64. doi: 10.1021/jo902084j.
10
Metal-organic cooperative catalysis in C-H and C-C bond activation and its concurrent recovery.金属有机协同催化在C-H和C-C键活化及其同步回收中的应用
Acc Chem Res. 2008 Feb;41(2):222-34. doi: 10.1021/ar700133y. Epub 2008 Feb 2.

引用本文的文献

1
Iridium porphyrin-catalysed asymmetric carbene insertion into primary N-adjacent C-H bonds with TON over 1000000.铱卟啉催化卡宾对一级N-邻位C-H键的不对称插入反应,其催化转化数超过1000000。
Nat Commun. 2025 Apr 7;16(1):3311. doi: 10.1038/s41467-025-58316-1.
2
C-H Bonds as Functional Groups: Simultaneous Generation of Multiple Stereocenters by Enantioselective Hydroxylation at Unactivated Tertiary C-H Bonds.作为官能团的碳氢键:通过对未活化叔碳氢键进行对映选择性羟基化同时生成多个立体中心
J Am Chem Soc. 2023 Jul 26;145(29):15742-15753. doi: 10.1021/jacs.2c10148. Epub 2023 Jul 11.
3
Chiral Bismuth-Rhodium Paddlewheel Complexes Empowered by London Dispersion: The C-H Functionalization Nexus.
手性铋-铑桨轮配合物受伦敦色散作用的影响:C-H 功能化连接点。
Angew Chem Int Ed Engl. 2022 Nov 7;61(45):e202212546. doi: 10.1002/anie.202212546. Epub 2022 Oct 11.
4
Helicity Modulation in NIR-Absorbing Porphyrin-Ryleneimides.近红外吸收卟啉-苝酰亚胺中的螺旋度调制
Angew Chem Int Ed Engl. 2022 Apr 25;61(18):e202200781. doi: 10.1002/anie.202200781. Epub 2022 Feb 24.
5
Dirhodium tetracarboxylates as catalysts for selective intermolecular C-H functionalization.四羧基二铑作为选择性分子间C-H官能化反应的催化剂。
Nat Rev Chem. 2019 Jun;3(6):347-360. doi: 10.1038/s41570-019-0099-x. Epub 2019 May 7.
6
Design of catalysts for site-selective and enantioselective functionalization of non-activated primary C-H bonds.非活化一级 C-H 键的选择性和对映选择性功能化的催化剂设计。
Nat Chem. 2018 Oct;10(10):1048-1055. doi: 10.1038/s41557-018-0087-7. Epub 2018 Aug 6.
7
Iridium(iii)-bis(imidazolinyl)phenyl catalysts for enantioselective C-H functionalization with ethyl diazoacetate.用于与重氮乙酸乙酯进行对映选择性C-H官能化反应的铱(III)-双(咪唑啉基)苯基催化剂
Chem Sci. 2016 May 1;7(5):3142-3146. doi: 10.1039/c6sc00190d. Epub 2016 Feb 5.
8
Challenges and opportunities for alkane functionalisation using molecular catalysts.使用分子催化剂进行烷烃官能团化的挑战与机遇
Chem Sci. 2017 Nov 9;9(2):288-299. doi: 10.1039/c7sc03610h. eCollection 2018 Jan 14.
9
Enantioselective carbenoid insertion into C(sp(3))-H bonds.对映选择性类卡宾插入到C(sp(3))-H键中。
Beilstein J Org Chem. 2016 May 4;12:882-902. doi: 10.3762/bjoc.12.87. eCollection 2016.
10
Recent advances in C(sp(3))-H bond functionalization via metal-carbene insertions.通过金属卡宾插入实现C(sp(3))-H键官能团化的最新进展。
Beilstein J Org Chem. 2016 Apr 25;12:796-804. doi: 10.3762/bjoc.12.78. eCollection 2016.