活性中心构型对共聚单体反应活性的影响：以ε-己内酯/L,L-丙交酯共聚反应为例 - Suppr

Effect of the configuration of the active center on comonomer reactivities: the case of epsilon-caprolactone/L,L-lactide copolymerization.

作者信息

Florczak Marcin, Duda Andrzej

机构信息

Department of Polymer Chemistry, Centre of Molecular and Macromolecular Studies, Polish Academy of Sciences, ul. Sienkiewicza 112, 90-363 Lodz, Poland.

出版信息

Angew Chem Int Ed Engl. 2008;47(47):9088-91. doi: 10.1002/anie.200803540.

DOI:10.1002/anie.200803540

PMID:18924205

Abstract

摘要

相似文献

Effect of the configuration of the active center on comonomer reactivities: the case of epsilon-caprolactone/L,L-lactide copolymerization.活性中心构型对共聚单体反应活性的影响：以ε-己内酯/L,L-丙交酯共聚反应为例

Angew Chem Int Ed Engl. 2008;47(47):9088-91. doi: 10.1002/anie.200803540.

Structural characterization of a lipase-catalyzed copolymerization of epsilon-caprolactone and D,L-lactide.脂肪酶催化的ε-己内酯与D,L-丙交酯共聚反应的结构表征

Biomacromolecules. 2003 Jul-Aug;4(4):1068-71. doi: 10.1021/bm0340725.

The effect of epsilon-caproyl/D,L-lactyl unit composition on the hydrolytic degradation of poly(D,L-lactide-ran-epsilon-caprolactone)-poly(ethylene glycol)-poly(D,L-lactide-ran-epsilon-caprolactone).ε-己酰基/D,L-丙交酯单元组成对聚（D,L-丙交酯-无规-ε-己内酯）-聚乙二醇-聚（D,L-丙交酯-无规-ε-己内酯）水解降解的影响

Biomaterials. 2006 Feb;27(4):544-52. doi: 10.1016/j.biomaterials.2005.06.026. Epub 2005 Aug 15.

Alkaline and enzymatic degradation of L-lactide copolymers, 1. Amorphous-made films of L-lactide copolymers with D-lactide, glycolide, and epsilon-caprolactone.L-丙交酯共聚物的碱性和酶促降解，1. 由L-丙交酯与D-丙交酯、乙交酯和ε-己内酯制成的非晶态薄膜。

Macromol Biosci. 2005 Feb 23;5(2):135-48. doi: 10.1002/mabi.200400154.

Hydrolytic degradation of composites of poly(L-lactide-co-epsilon-caprolactone) 70/30 and β-tricalcium phosphate.聚（L-丙交酯-共-ε-己内酯）70/30 与 β-磷酸三钙复合材料的水解降解。

J Biomater Appl. 2013 Nov;28(4):529-43. doi: 10.1177/0885328212462258. Epub 2012 Oct 9.

Rapidly degraded terpolymers of dl-lactide, glycolide, and epsilon-caprolactone with increased hydrophilicity by copolymerization with polyethers.通过与聚醚共聚而具有更高亲水性的dl-丙交酯、乙交酯和ε-己内酯的快速降解三元共聚物。

J Biomed Mater Res. 1990 Oct;24(10):1397-411. doi: 10.1002/jbm.820241011.

Synthesis of the star-shaped copolymer of epsilon-caprolactone and L-lactide from a cyclotriphosphazene core.由环三磷腈核合成ε-己内酯与L-丙交酯的星形共聚物。

Biomacromolecules. 2003 Nov-Dec;4(6):1491-4. doi: 10.1021/bm034237+.

Synthesis, structure and properties of poly(L-lactide-co-ε-caprolactone) statistical copolymers.聚（L-丙交酯-共-ε-己内酯）统计共聚物的合成、结构和性能。

J Mech Behav Biomed Mater. 2012 May;9:100-12. doi: 10.1016/j.jmbbm.2012.01.003. Epub 2012 Jan 18.

Morphology of elastic poly(L-lactide-co-epsilon-caprolactone) copolymers and in vitro and in vivo degradation behavior of their scaffolds.弹性聚（L-丙交酯-共-ε-己内酯）共聚物的形态及其支架的体外和体内降解行为

Biomacromolecules. 2004 Jul-Aug;5(4):1303-9. doi: 10.1021/bm049921i.

Poly(ether-ester) conjugates with enhanced degradation.具有增强降解性能的聚（醚-酯）共轭物。

Biomacromolecules. 2008 Oct;9(10):2954-62. doi: 10.1021/bm8007499. Epub 2008 Sep 20.

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Effect of the configuration of the active center on comonomer reactivities: the case of epsilon-caprolactone/L,L-lactide copolymerization.

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