Department of Chemistry, Fudan University, 220 Handan Road, Shanghai 200433, P.R.China.
Beilstein J Org Chem. 2008;4:27. doi: 10.3762/bjoc.4.27. Epub 2008 Jul 30.
Ru(3)(CO)(12)/EtI has been found to be an efficient catalyst system for the dehydrosilylation of carboxylic acids with silanes. In the presence of 1 mol% Ru(3)(CO)(12) and 4 mol% EtI, dehydrosilylation reactions in toluene afforded the corresponding silyl esters at 100 degrees C in good and high yields.
研究发现 Ru(3)(CO)(12)/EtI 是一种有效的用于羧酸和硅烷的脱硅反应的催化剂体系。在 1 mol% Ru(3)(CO)(12)和 4 mol% EtI 的存在下，在甲苯中，脱硅反应在 100°C 下以良好和高产率得到相应的硅基酯。
Zotero 插件