钯催化烯烃双官能团化反应的机理研究方法。
Mechanistic approaches to palladium-catalyzed alkene difunctionalization reactions.
作者信息
Jensen Katrina H, Sigman Matthew S
机构信息
Department of Chemistry, University of Utah, 315 South 1400 East, Salt Lake City, USA.
出版信息
Org Biomol Chem. 2008 Nov 21;6(22):4083-8. doi: 10.1039/b813246a. Epub 2008 Oct 9.
Abstract
Alkene difunctionalization, the addition of two functional groups across a double bond, exemplifies a class of reactions with significant synthetic potential. This emerging area examines recent developments of palladium-catalyzed difunctionalization reactions, with a focus on mechanistic strategies that allow for functionalization of a common palladium alkyl intermediate.
摘要
烯烃双官能团化反应，即在双键两端添加两个官能团，是一类具有重大合成潜力的反应。这一新兴领域研究了钯催化双官能团化反应的最新进展，重点关注能够实现常见钯烷基中间体官能团化的机理策略。
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