用于高效染料敏化太阳能电池的富电子杂芳族共轭联吡啶基钌敏化剂。
Electron-rich heteroaromatic conjugated bipyridine based ruthenium sensitizer for efficient dye-sensitized solar cells.
作者信息
Abbotto Alessandro, Barolo Claudia, Bellotto Luca, De Angelis Filippo, Grätzel Michael, Manfredi Norberto, Marinzi Chiara, Fantacci Simona, Yum Jun-Ho, Nazeeruddin Mohammad K
机构信息
Department of Materials Science and INSTM, University of Milano-Bicocca, Milan, Italy.
出版信息
Chem Commun (Camb). 2008 Nov 14(42):5318-20. doi: 10.1039/b811378e. Epub 2008 Sep 16.
A novel heteroleptic ruthenium complex carrying a heteroaromatic-4,4'-pi-conjugated 2,2'-bipyridine [Ru(II)LL'(NCS)(2)] (L = 4,4'-bis[(E)-2-(3,4-ethylenedioxythien-2-yl)vinyl]-2,2'-bipyridine, L' = 4,4'-(dicarboxylic acid)-2,2'-bipyridine) was synthesized and used in dye-sensitized solar cells, yielding photovoltaic efficiencies of 9.1% under standard global AM 1.5 sunlight.
一种携带杂芳族-4,4'-π共轭2,2'-联吡啶的新型异质钌配合物[Ru(II)LL'(NCS)(2)]（L = 4,4'-双[(E)-2-(3,4-亚乙基二氧噻吩-2-基)乙烯基]-2,2'-联吡啶，L' = 4,4'-(二羧酸)-2,2'-联吡啶）被合成并用于染料敏化太阳能电池，在标准全球AM 1.5太阳光下产生的光伏效率为9.1%。
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