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一种新型钌敏化剂，具有用于高效染料敏化TiO2太阳能电池的疏水性2-噻吩-2-基-乙烯基共轭联吡啶配体。

A novel ruthenium sensitizer with a hydrophobic 2-thiophen-2-yl-vinyl-conjugated bipyridyl ligand for effective dye sensitized TiO2 solar cells.

作者信息

Jiang Ke-Jian, Masaki Naruhiko, Xia Jiang-Bin, Noda Shuji, Yanagida Shozo

机构信息

Center for Advanced Science and Innovation, Osaka University, Yamada-oka 2-1, Suita, Osaka, 565-0871, Japan.

出版信息

Chem Commun (Camb). 2006 Jun 21(23):2460-2. doi: 10.1039/b602989b. Epub 2006 May 3.

DOI:10.1039/b602989b
PMID:16758015
Abstract

A hydrophobic and 2-thiophen-2-yl-vinyl-conjugated ruthenium complex, cis-Ru(dhtbpy)(dcbpy)(NCS)2 [dhtbpy = 4,4'-di(hexylthienylvinyl)-2,2'-bipyridyl; dcbpy = 4,4'-dicarboxy-2,2'-bipyridyl], was newly designed, synthesized and applied successfully to sensitization of nanocrystalline TiO2-based solar cells, giving a conversion efficiency of 9.5% under irradiation with AM 1.5 solar light.

摘要

一种疏水且含有2-噻吩-2-基乙烯基共轭的钌配合物，顺式-Ru(dhtbpy)(dcbpy)(NCS)2 [dhtbpy = 4,4'-二(己基噻吩基乙烯基)-2,2'-联吡啶；dcbpy = 4,4'-二羧基-2,2'-联吡啶]，被新设计、合成并成功应用于纳米晶二氧化钛基太阳能电池的敏化，在AM 1.5太阳光照射下转换效率达9.5%。

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