Beyler Maryline, Heitz Valérie, Sauvage Jean-Pierre
Laboratoire de Chimie Organo-Minérale, LC3 UMR 7177 du CNRS, Université Louis Pasteur, Institut de Chimie, 4 rue Blaise Pascal, Strasbourg Cedex, France.
Chem Commun (Camb). 2008 Nov 14(42):5396-8. doi: 10.1039/b811013a. Epub 2008 Sep 17.
A [2]catenane is formed quantitatively by mixing substituted 1,10-phenanthroline-based chelates with copper(I) acting as central template, the ring-forming reaction being based on the coordination of pyridinic bidentate ligands onto the zinc atoms of the four porphyrins surrounding the core of the molecule.
通过将基于取代的1,10 - 菲咯啉的螯合物与作为中心模板的铜（I）混合，定量形成了一种[2]连环烷，成环反应基于吡啶双齿配体与围绕分子核心的四个卟啉的锌原子的配位作用。
