ICBMS, Université Lyon 1, CNRS, Laboratoire SERCOF, 43 boulevard du 11 novembre 1918, Villeurbanne, F-69622 France.
J Org Chem. 2008 Dec 5;73(23):9362-5. doi: 10.1021/jo8018544.
Fluorinated moieties constitute important substituents used in many applications to modify the properties of molecules. The action of DAST onto Ruppert's reagent yields to a not isolable intermediate that can then react with various primary amines to give trifluoromethanesulfinamidines and trifluoromethanesulfanylamides. Such compounds were unknown until now and constitute interesting new families of fluorinated molecules.
氟代部分是许多应用中用来修饰分子性质的重要取代基。DAST 与 Ruppert 试剂反应生成一个不可分离的中间体，该中间体可以与各种伯胺反应生成三氟甲磺酰亚胺和三氟甲硫酰胺。这些化合物直到现在才被发现，它们构成了有趣的新的氟代分子家族。
