Institute of Chemistry and Biochemistry (ICBMS - UMR CNRS 5246), Université de Lyon, Université Lyon 1, CNRS, 43 Bd du 11 novembre 1918 - 69622 Lyon, France ; CERMEP - in vivo imaging, Groupement Hospitalier Est, 59 Bd Pinel - 69003 Lyon, France.
Institute of Chemistry and Biochemistry (ICBMS - UMR CNRS 5246), Université de Lyon, Université Lyon 1, CNRS, 43 Bd du 11 novembre 1918 - 69622 Lyon, France.
Beilstein J Org Chem. 2013 Nov 4;9:2354-7. doi: 10.3762/bjoc.9.270. eCollection 2013.
The CF3SN moiety is a substituent with interesting properties. However, there is no easy synthetic access to molecules bearing this group. The trifluoromethanesulfenamide is a new reagent for the electrophilic trifluoromethylthiolation which reacts easily with amines to obtain trifluoromethylsulfanylamines with good yields.
CF3SN 部分是一种具有有趣性质的取代基。然而，没有简单的合成方法可以得到带有这个基团的分子。三氟甲硫基酰胺是一种新的亲电三氟甲基化试剂，它很容易与胺反应，以良好的收率得到三氟甲硫基胺。
