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一种具有[HS-LS-LS]中间相的两步自旋交叉单核铁（II）配合物。

A two-step spin crossover mononuclear iron(II) complex with a [HS-LS-LS] intermediate phase.

作者信息

Bonnet Sylvestre, Siegler Maxime A, Costa José Sánchez, Molnár Gábor, Bousseksou Azzedine, Spek Anthony L, Gamez Patrick, Reedijk Jan

机构信息

Leiden Institute of Chemistry, Leiden University, RA2300, Leiden, The Netherlands.

出版信息

Chem Commun (Camb). 2008 Nov 21(43):5619-21. doi: 10.1039/b811746b. Epub 2008 Sep 29.

DOI:10.1039/b811746b
PMID:18997971
Abstract

The two-step spin crossover of a new mononuclear iron(ii) complex is studied by magnetic, crystallographic and calorimetric methods revealing two successive first-order phase transitions and an ordered intermediate phase built by the repetition of the unprecedented [HS-LS-LS] motif.

摘要

通过磁性、晶体学和量热法研究了一种新型单核铁（II）配合物的两步自旋交叉现象，揭示了两个连续的一级相变以及一个由前所未有的[高自旋-低自旋-低自旋]基序重复构建的有序中间相。

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