Stevenson Jacob D, Walczak Aleksandra M, Hall Randall W, Wolynes Peter G
Department of Physics, University of California, San Diego, La Jolla, California 92093, USA.
J Chem Phys. 2008 Nov 21;129(19):194505. doi: 10.1063/1.3009827.
By defining a spatially varying replica overlap parameter for a supercooled liquid referenced to an ensemble of fiducial liquid state configurations, we explicitly construct a constrained replica free energy functional that maps directly onto an Ising Hamiltonian with both random fields and random interactions whose statistics depend on the liquid structure. Renormalization group results for random magnets when combined with these statistics for the Lennard-Jones glass suggest that discontinuous replica symmetry breaking would occur if a liquid with short range interactions could be equilibrated at a sufficiently low temperature where its mean field configurational entropy would vanish, even though the system strictly retains a finite configurational entropy.
通过为过冷液体定义一个相对于基准液态构型系综的空间变化的复本重叠参数,我们明确构建了一个受约束的复本自由能泛函,它直接映射到一个具有随机场和随机相互作用的伊辛哈密顿量上,其统计特性取决于液体结构。当随机磁体的重整化群结果与这些 Lennard-Jones 玻璃的统计特性相结合时表明,如果具有短程相互作用的液体能够在足够低的温度下达到平衡,此时其平均场构型熵将消失,即使系统严格保留有限的构型熵,也会发生不连续的复本对称性破缺。