• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

1,8-双（二苯基膦基）萘/三（五氟苯基）硼烷对的异裂二氢活化及其在硅烯醇醚无金属催化氢化中的应用

Heterolytic dihydrogen activation with the 1,8-bis(diphenylphosphino)naphthalene/B(C6F5)3 pair and its application for metal-free catalytic hydrogenation of silyl enol ethers.

作者信息

Wang Huadong, Fröhlich Roland, Kehr Gerald, Erker Gerhard

机构信息

Organisch-Chemisches Institut, Universität Münster, Corrensstr. 40, D-48149, Münster, Germany.

出版信息

Chem Commun (Camb). 2008 Dec 7(45):5966-8. doi: 10.1039/b813286k. Epub 2008 Oct 9.

DOI:10.1039/b813286k
PMID:19030554
Abstract

The "frustrated Lewis pair" 1,8-bis(diphenylphosphino)naphthalene/B(C6F5)3 reversibly activates dihydrogen; it serves as an active catalyst for the hydrogenation of silyl enol ethers under mild reaction conditions.

摘要

“受阻路易斯酸碱对”1,8 - 双（二苯基膦基）萘/B（C6F5）3可使氢气可逆活化；在温和的反应条件下，它可作为硅基烯醇醚氢化反应的活性催化剂。

相似文献

1
Heterolytic dihydrogen activation with the 1,8-bis(diphenylphosphino)naphthalene/B(C6F5)3 pair and its application for metal-free catalytic hydrogenation of silyl enol ethers.1,8-双（二苯基膦基）萘/三（五氟苯基）硼烷对的异裂二氢活化及其在硅烯醇醚无金属催化氢化中的应用
Chem Commun (Camb). 2008 Dec 7(45):5966-8. doi: 10.1039/b813286k. Epub 2008 Oct 9.
2
Catalytic hydrogenation of sensitive organometallic compounds by antagonistic N/B Lewis pair catalyst systems.
J Am Chem Soc. 2009 Mar 18;131(10):3454-5. doi: 10.1021/ja8100006.
3
A highly enantioselective hydrogenation of silyl enol ethers catalyzed by chiral frustrated Lewis pairs.手性受阻路易斯对催化的硅基烯醇醚的高对映选择性氢化。
J Am Chem Soc. 2014 Sep 3;136(35):12261-4. doi: 10.1021/ja507536n. Epub 2014 Aug 21.
4
FLP-Catalyzed Transfer Hydrogenation of Silyl Enol Ethers.FLP催化的硅基烯醇醚转移氢化反应。
Angew Chem Int Ed Engl. 2018 Sep 17;57(38):12356-12359. doi: 10.1002/anie.201808800. Epub 2018 Aug 24.
5
Frustrated Lewis pairs: metal-free hydrogen activation and more.受阻路易斯对：无金属氢活化及更多。
Angew Chem Int Ed Engl. 2010;49(1):46-76. doi: 10.1002/anie.200903708.
6
Internal adduct formation of active intramolecular C4-bridged frustrated phosphane/borane Lewis pairs.活性分子内 C4-桥联受阻膦/硼烷路易斯对的内加合物形成。
J Am Chem Soc. 2014 Feb 26;136(8):3293-303. doi: 10.1021/ja413060u. Epub 2014 Feb 12.
7
B(C6F5)3-catalyzed transfer hydrogenation of imines and related heteroarenes using cyclohexa-1,4-dienes as a dihydrogen source.B(C6F5)3 催化的亚胺及相关杂环芳烃的转移氢化反应，使用环己二烯作为双氢源。
Angew Chem Int Ed Engl. 2015 Feb 2;54(6):1965-8. doi: 10.1002/anie.201409246. Epub 2014 Dec 21.
8
Lewis base activation of Lewis acids. Catalytic enantioselective addition of silyl enol ethers of achiral methyl ketones to aldehydes.路易斯酸的路易斯碱活化。非手性甲基酮的硅烯醇醚对醛的催化对映选择性加成。
Org Lett. 2003 Jun 26;5(13):2303-6. doi: 10.1021/ol034641l.
9
On the mechanism of B(C6F5)3-catalyzed direct hydrogenation of imines: inherent and thermally induced frustration.关于B(C6F5)3催化亚胺直接氢化反应的机理：内在及热诱导的受阻现象
J Am Chem Soc. 2009 Feb 11;131(5):2029-36. doi: 10.1021/ja809125r.
10
Facile development of chiral alkenylboranes from chiral diynes for asymmetric hydrogenation of silyl enol ethers.手性二炔构建手性烯基硼试剂在硅基烯醇醚不对称氢化反应中的应用
Org Lett. 2015 Feb 20;17(4):990-3. doi: 10.1021/acs.orglett.5b00085. Epub 2015 Feb 3.

引用本文的文献

1
Computational Design of Frustrated Lewis Pairs as a Strategy for Catalytic Hydrogen Activation and Hydrogenation Catalyst.受阻路易斯酸碱对的计算设计作为催化氢活化和氢化催化剂的一种策略
ACS Omega. 2023 Feb 23;8(9):8488-8496. doi: 10.1021/acsomega.2c07442. eCollection 2023 Mar 7.
2
Exploring the Reactivity of B-Connected Carboranylphosphines in Frustrated Lewis Pair Chemistry: A New Frame for a Classic System.探索硼连接的碳硼烷膦在受阻路易斯酸碱对化学中的反应活性：经典体系的新框架。
Chemistry. 2022 Jun 15;28(34):e202200531. doi: 10.1002/chem.202200531. Epub 2022 May 12.
3
Exploring the Reactivity of a Frustrated Sn/P Lewis Pair: The Highly Selective Complexation of the cis-Azobenzene Photoisomer.
探索受阻Sn/P路易斯酸碱对的反应活性：顺式偶氮苯光异构体的高度选择性络合
Chemistry. 2021 Feb 19;27(11):3793-3798. doi: 10.1002/chem.202004600. Epub 2021 Jan 28.
4
A Zwitterionic Phosphonium Stannate(II) via Hydrogen Splitting by a Sn/P Frustrated Lewis-Pair and Reductive Elimination.一种通过锡/磷受阻路易斯酸碱对的氢分裂和还原消除形成的两性离子锡酸鏻（II）
Chemistry. 2020 Dec 23;26(72):17381-17385. doi: 10.1002/chem.202004425. Epub 2020 Nov 23.
5
Semihydrogenation of Alkynes Catalyzed by a Pyridone Borane Complex: Frustrated Lewis Pair Reactivity and Boron-Ligand Cooperation in Concert.吡啶硼烷配合物催化的炔烃半氢化反应：受阻路易斯酸碱对协同反应及硼配体协同作用
Chemistry. 2020 Oct 21;26(59):13445-13450. doi: 10.1002/chem.202001276. Epub 2020 Sep 18.
6
An Isolable Bis(Silanone-Borane) Adduct.一种可分离的双（硅酮-硼烷）加合物。
Chemistry. 2020 Apr 6;26(20):4500-4504. doi: 10.1002/chem.202000235. Epub 2020 Mar 11.
7
FLP-Catalyzed Transfer Hydrogenation of Silyl Enol Ethers.FLP催化的硅基烯醇醚转移氢化反应。
Angew Chem Int Ed Engl. 2018 Sep 17;57(38):12356-12359. doi: 10.1002/anie.201808800. Epub 2018 Aug 24.
8
A family of N-heterocyclic carbene-stabilized borenium ions for metal-free imine hydrogenation catalysis.用于无金属亚胺氢化催化的N-杂环卡宾稳定的硼正离子家族。
Chem Sci. 2015 Mar 1;6(3):2010-2015. doi: 10.1039/c4sc03675a. Epub 2015 Jan 26.
9
Heterolytic Splitting of Molecular Hydrogen by Frustrated and Classical Lewis Pairs: A Unified Reactivity Concept.受阻路易斯酸碱对和经典路易斯酸碱对引发的氢分子异裂：统一的反应性概念
Sci Rep. 2017 Nov 22;7(1):16024. doi: 10.1038/s41598-017-16244-1.
10
Crystal structure of (n-but-yl)[2-(2,6-di-meth-oxy-phen-yl)-6-methyl-phen-yl](2-meth-oxy-phen-yl)phospho-nium chloride monohydrate.一水合氯化（正丁基）[2-（2,6-二甲氧基苯基）-6-甲基苯基]（2-甲氧基苯基）鏻的晶体结构
Acta Crystallogr E Crystallogr Commun. 2016 Jan 13;72(Pt 2):174-7. doi: 10.1107/S2056989015024780. eCollection 2016 Feb 1.