1,8-双（二苯基膦基）萘/三（五氟苯基）硼烷对的异裂二氢活化及其在硅烯醇醚无金属催化氢化中的应用
Heterolytic dihydrogen activation with the 1,8-bis(diphenylphosphino)naphthalene/B(C6F5)3 pair and its application for metal-free catalytic hydrogenation of silyl enol ethers.
作者信息
Wang Huadong, Fröhlich Roland, Kehr Gerald, Erker Gerhard
机构信息
Organisch-Chemisches Institut, Universität Münster, Corrensstr. 40, D-48149, Münster, Germany.
出版信息
Chem Commun (Camb). 2008 Dec 7(45):5966-8. doi: 10.1039/b813286k. Epub 2008 Oct 9.
DOI:10.1039/b813286k
PMID:19030554
Abstract
The "frustrated Lewis pair" 1,8-bis(diphenylphosphino)naphthalene/B(C6F5)3 reversibly activates dihydrogen; it serves as an active catalyst for the hydrogenation of silyl enol ethers under mild reaction conditions.
摘要
“受阻路易斯酸碱对”1,8 - 双（二苯基膦基）萘/B（C6F5）3可使氢气可逆活化；在温和的反应条件下，它可作为硅基烯醇醚氢化反应的活性催化剂。
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