Gauthier Marc A, Gibson Matthew I, Klok Harm-Anton
Ecole Polytechnique Fédérale de Lausanne, Institut des Matériaux, Laboratoire des Polymères, Bâtiment MXD, Station 12, 1015 Lausanne, Switzerland.
Angew Chem Int Ed Engl. 2009;48(1):48-58. doi: 10.1002/anie.200801951.
Post-polymerization modification is based on the direct polymerization or copolymerization of monomers bearing chemoselective handles that are inert towards the polymerization conditions but can be quantitatively converted in a subsequent step into a broad range of other functional groups. The success of this method is based on the excellent conversions achievable under mild conditions, the excellent functional-group tolerance, and the orthogonality of the post-polymerization modification reactions. This Review surveys different classes of reactive polymer precursors bearing chemoselective handles and discusses issues related to the preparation of these reactive polymers by direct polymerization of appropriately functionalized monomers as well as the post-polymerization modification of these precursors into functional polymers.
聚合后修饰基于带有化学选择性官能团的单体的直接聚合或共聚，这些官能团对聚合条件呈惰性，但可在后续步骤中定量转化为多种其他官能团。该方法的成功基于在温和条件下可实现的优异转化率、出色的官能团耐受性以及聚合后修饰反应的正交性。本综述概述了带有化学选择性官能团的不同类型的反应性聚合物前体，并讨论了通过适当官能化单体的直接聚合制备这些反应性聚合物以及将这些前体聚合后修饰为功能聚合物的相关问题。
