D'Orsogna Maria R, Chou Tom, Antal Tibor
Department of Mathematics, UCLA, Los Angeles, CA 90095-1555.
J Phys A Math Gen. 2007 May 25;40(21):5575-5584. doi: 10.1088/1751-8113/40/21/009.
We solve the problem of discrete translocation of a polymer through a pore, driven by the irreversible, random sequential adsorption of particles on one side of the pore. Although the kinetics of the wall motion and the deposition are coupled, we find the exact steady-state distribution for the gap between the wall and the nearest deposited particle. This result enables us to construct the mean translocation velocity demonstrating that translocation is faster when the adsorbing particles are smaller. Monte-Carlo simulations also show that smaller particles gives less dispersion in the ratcheted motion. We also define and compare the relative efficiencies of ratcheting by deposition of particles with different sizes and we describe an associated "zone-refinement" process.
我们解决了聚合物通过孔隙的离散易位问题,该过程由孔隙一侧颗粒的不可逆随机顺序吸附驱动。尽管壁运动和沉积的动力学是耦合的,但我们找到了壁与最近沉积颗粒之间间隙的精确稳态分布。这一结果使我们能够构建平均易位速度,表明当吸附颗粒较小时易位速度更快。蒙特卡罗模拟还表明,较小的颗粒在棘轮运动中的分散性较小。我们还定义并比较了不同尺寸颗粒沉积产生棘轮效应的相对效率,并描述了相关的“区域细化”过程。