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Ruthenium complexes with cooperative PNP ligands: bifunctional catalysts for the dehydrogenation of ammonia-borane.

作者信息

Käss Martina, Friedrich Anja, Drees Markus, Schneider Sven

机构信息

Department Chemie, Technische Universität München, Lichtenbergstrasse 4, 85748 Garching b. München, Germany.

出版信息

Angew Chem Int Ed Engl. 2009;48(5):905-7. doi: 10.1002/anie.200805108.

DOI:10.1002/anie.200805108
PMID:19116993
Abstract
摘要

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Ruthenium complexes with cooperative PNP ligands: bifunctional catalysts for the dehydrogenation of ammonia-borane.具有协同PNP配体的钌配合物：用于氨硼烷脱氢的双功能催化剂。
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Reaction of a P/Al-based frustrated Lewis pair with ammonia, borane, and amine-boranes: adduct formation and catalytic dehydrogenation.基于磷/铝的受阻路易斯酸碱对与氨、硼烷和胺硼烷的反应：加合物形成及催化脱氢反应
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