质子和电子的金属-配体协同转移
Metal-Ligand Cooperative Transfer of Protons and Electrons.
作者信息
Anferov Sophie W, Czaikowski Maia E, Anderson John S
机构信息
University of Chicago Department of Chemistry, 929 E 57th St. Chicago, IL, 60637.
出版信息
Trends Chem. 2021 Dec;3(12):993-996. doi: 10.1016/j.trechm.2021.10.002. Epub 2021 Oct 22.
Abstract
Realizing cooperativity between ligands and metal centers in the transfer of proton and electron equivalents has the potential to facilitate faster, selective, and novel transformations. Recent advances in the synthesis and application of ligands with these design features illustrate the value of this biomimetic strategy in synthetic chemistry.
摘要
实现配体与金属中心在质子和电子当量转移过程中的协同作用，有可能促进更快、更具选择性的新型转化反应。具有这些设计特点的配体在合成与应用方面的最新进展，说明了这种仿生策略在合成化学中的价值。
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