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[含二元溶液的单膜系统中浓度边界层厚度的估算方法]

[Estimation method of the concentration boundary layers thicknesses in a single-membrane system containing binary solutions].

作者信息

Slezak Andrzej

机构信息

Katedra Zdrowia Publicznego, Zakład Biofizyki, Wydział Zarzadzania Politechnika Czestochowska, Czestochowa.

出版信息

Polim Med. 2008;38(3):47-51.

PMID:19137976
Abstract

On a basis of the Kedem-Katchalsky formalism, the estimation method of the concentration boundary layers thicknesses (delta) in a single-membrane system containing binary solutions was devised. Mathematical formula, which is a basis of this method, contains transport membrane (L(p), sigma, omega) and solution (D, C) parameters and volume osmotic flux (J(v)). These values can be determined in a series of independent experiments. Calculated values (delta) are nonlinearly dependent on concentrations of investigated solutions and membrane system configuration. These nonlinearities are an effect of a competition between spontaneously occurring diffusion and convection processes.

摘要

基于 Kedem-Katchalsky 形式理论,设计了一种估算包含二元溶液的单膜系统中浓度边界层厚度(δ)的方法。作为该方法基础的数学公式包含传输膜(L(p)、σ、ω)和溶液(D、C)参数以及体积渗透通量(J(v))。这些值可通过一系列独立实验来确定。计算得到的(δ)值与所研究溶液的浓度和膜系统构型呈非线性相关。这些非线性是自发扩散和对流过程之间竞争的结果。

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