White Robin J, Luque Rafael, Budarin Vitaliy L, Clark James H, Macquarrie Duncan J
Green Chemistry Centre of Excellence, The University of York, York, UK YO10 5DD.
Chem Soc Rev. 2009 Feb;38(2):481-94. doi: 10.1039/b802654h. Epub 2008 Dec 18.
Nanoparticles are regarded as a major step forward to achieving the miniaturisation and nanoscaling effects and properties that have been utilised by nature for millions of years. The chemist is no longer observing and describing the behaviour of matter but is now able to manipulate and produce new types of materials with specific desired physicochemical characteristics. Such materials are receiving extensive attention across a broad range of research disciplines. The fusion between nanoparticle and nanoporous materials technology represents one of the most interesting of these rapidly expanding areas. The harnessing of nanoscale activity and selectivity, potentially provides extremely efficient catalytic materials for the production of commodity chemicals, and energy needed for a future sustainable society. In this tutorial review, we present an introduction to the field of supported metal nanoparticles (SMNPs) on porous materials, focusing on their preparation and applications in different areas.
纳米颗粒被视为在实现小型化以及纳米级效应和特性方面向前迈出的重要一步,而这些效应和特性已被自然界利用了数百万年。化学家不再只是观察和描述物质的行为,而是现在能够操纵并生产出具有特定所需物理化学特性的新型材料。这类材料在广泛的研究领域中受到了广泛关注。纳米颗粒与纳米多孔材料技术的融合是这些迅速发展的领域中最有趣的领域之一。利用纳米级活性和选择性,有可能为商品化学品的生产以及未来可持续社会所需的能源提供极其高效的催化材料。在本专题综述中,我们介绍了多孔材料负载金属纳米颗粒(SMNP)领域,重点关注其制备及其在不同领域的应用。