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在过氧化氢存在下,美他环素、土霉素和金霉素铕配合物的光学性质。

Optical properties of metacycline, oxytetracycline and chlortetracycline europium complexes in the presence of hydrogen peroxide.

作者信息

Grasso Andrea Nastri, Teixeira Luciane dos Santos, Vieira Nilson Dias, Courrol Lilia Coronato

机构信息

Centro de Lasers e Aplicações, IPEN/CNEN-SP, Av. Lineu Prestes 2242-Cidade Universitária, São Paulo, SP, Brazil.

出版信息

J Fluoresc. 2009 Jul;19(4):715-21. doi: 10.1007/s10895-009-0465-z. Epub 2009 Jan 28.

Abstract

Tetracycline possesses a great tendency to form complexes with a number of chemical species, particularly with Eu3+ ions. In this work we investigate the europium optical properties of three tetracyclines europium complexes: Metacycline (MTc), Oxytetracycline (OTc), and Chlortetracycline (CTc), in the presence and absence of hydrogen peroxide (HP). The results show that the emission band of EuOTc have enhancement in the presence of hydrogen peroxide. A calibration curve was shown for this complex with the best molar ratio obtained.

摘要

四环素极易与许多化学物质形成络合物,尤其是与Eu3+离子。在本研究中,我们研究了三种四环素铕络合物:美他环素(MTc)、土霉素(OTc)和金霉素(CTc)在有无过氧化氢(HP)存在下的铕光学性质。结果表明,在过氧化氢存在的情况下,EuOTc的发射带增强。给出了该络合物的校准曲线,并得到了最佳摩尔比。

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