联烯二醇的化学选择性和区域选择性钯催化氧环化反应：五元、六元和八元环的制备
Chemo- and regioselective palladium-catalyzed oxycyclization reactions of allendiols: preparation of five-, six-, and eight-membered cycles.
作者信息
Alcaide Benito, Almendros Pedro, Carrascosa Rocío, Martínez del Campo Teresa
机构信息
Departamento de Química Orgánica I, Facultad de Química, Universidad Complutense de Madrid, Spain.
出版信息
Chemistry. 2009 Mar 2;15(11):2496-9. doi: 10.1002/chem.200802675.
PMID:19185045
Abstract
Positive discrimination: Chemo- and regioselective palladium-catalyzed cycloetherification of allendiols, namely beta,gamma- and gamma,delta-allendiols, may occur by judicious choice of palladium-catalyzed conditions owing to their potential ability to discriminate between both nucleophilic sites (see scheme).
摘要
正性选择性
由于联烯二醇（即β,γ-和γ,δ-联烯二醇）在两个亲核位点之间具有潜在的区分能力，通过明智地选择钯催化条件，可能会发生化学选择性和区域选择性的钯催化环醚化反应（见反应式）。
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