钯催化杂环芳烃的苄基化反应。
Palladium-catalyzed benzylation of heterocyclic aromatic compounds.
机构信息
Center for Catalysis Research and Innovation, Department of Chemistry, University of Ottawa, 10 Marie Curie, Ottawa, ON, K1N 6J7, Canada.
出版信息
Org Lett. 2009 Sep 17;11(18):4160-3. doi: 10.1021/ol901689q.
PMID:19685908
Abstract
Broadly applicable palladium-catalyzed heteroarene benzylation reactions are described with a focus on the most challenging heterocyclic classes under traditional benzylation techniques such as sulfur-containing heterocycles and those bearing functional groups that would be incompatible with reactions requiring Lewis acids and/or strong bases.
摘要
本文介绍了广泛适用的钯催化杂芳烃苄基化反应，重点介绍了传统苄基化技术中最具挑战性的杂环类别，如含硫杂环和那些带有与需要路易斯酸和/或强碱的反应不相容的官能团的杂环。
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