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铜掺杂氮化硼纳米管微带的自组装与阴极发光

Self-assembly and cathodoluminescence of microbelts from Cu-doped boron nitride nanotubes.

作者信息

Chen Zhi-Gang, Zou Jin, Liu Qingfeng, Sun Chenghua, Liu Gang, Yao Xiangdong, Li Feng, Wu Bo, Yuan Xiao-Li, Sekiguchi Takashi, Cheng Hui-Ming, Lu Gao Qing

机构信息

Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China.

出版信息

ACS Nano. 2008 Aug;2(8):1523-32. doi: 10.1021/nn800211z.

Abstract

We report the self-assembly of microbelts from Cu-doped boron nitride nanotubes by chemical vapor deposition using Cu as a catalyst. The BN nanotubes with Cu-encapsulated flat tips have uniform outer diameters of approximately 240 nm, inner diameters of approximately 210 nm, and lengths of approximately 10 microm, and Cu is found to uniformly dope into the nanotubes. Most importantly, the nanotubes are self-assembled to form microbelts with 10 microm in width and tens of micrometers in length. Strong and tunable light emissions from the ultraviolet to visible light range are observed in such Cu-doped microbelts, showing their high potential for applications in lasing, light-emitting diode, and medical diagnosis devices.

摘要

我们报道了以铜为催化剂,通过化学气相沉积法实现铜掺杂氮化硼纳米管自组装形成微带。具有包裹铜的扁平尖端的氮化硼纳米管外径约为240纳米,内径约为210纳米,长度约为10微米,并且发现铜均匀地掺杂到纳米管中。最重要的是,这些纳米管自组装形成宽度为10微米、长度为几十微米的微带。在这种铜掺杂微带中观察到从紫外到可见光范围的强且可调谐的光发射,显示出它们在激光、发光二极管和医疗诊断设备应用中的巨大潜力。

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