Kokubo Masaya, Kobayashi Shū
Department of Chemistry, School of Science, The University of Tokyo, The HFRE Division, ERATO, JST, Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.
Chem Asian J. 2009 Apr 6;4(4):526-8. doi: 10.1002/asia.200800461.
Different in water! We have developed Nazarov-type reactions in water. Different reaction courses compared with those in organic solvents are observed in water. In the presence of a scandium based, surfactant-type catalyst, water-trapping products are obtained exclusively. The results presented are unprecedented and provide a valuable extension to information available regarding organic reactions in water.
水中的差异！我们已经开发出了在水中进行的纳扎罗夫型反应。在水中观察到与在有机溶剂中不同的反应过程。在一种基于钪的表面活性剂型催化剂存在下，仅得到水捕获产物。所呈现的结果是前所未有的，为有关水中有机反应的现有信息提供了有价值的扩展。
