Asymmetric Nazarov Cyclizations.
作者信息
Shimada Naoyuki, Stewart Craig, Tius Marcus A
机构信息
Department of Chemistry, University of Hawaii, 2545 The Mall, Honolulu, Hawaii 96822, U.S.A.
出版信息
Tetrahedron. 2011 Aug 19;67(33):5851-5870. doi: 10.1016/j.tet.2011.05.062.
Abstract
摘要
相似文献
1
Asymmetric Nazarov Cyclizations.不对称纳扎罗夫环化反应。
Tetrahedron. 2011 Aug 19;67(33):5851-5870. doi: 10.1016/j.tet.2011.05.062.
2
Recent Progress on Nazarov Cyclizations: The Use of Iron Salts as Catalysts in Ionic Liquid Solvent Systems.纳扎罗夫环化反应的最新进展：铁盐在离子液体溶剂体系中作为催化剂的应用
Chem Rec. 2016 Jun;16(3):1676-89. doi: 10.1002/tcr.201600021. Epub 2016 May 24.
3
Efficient Nazarov cyclizations of 2-alkoxy-1,4-pentadien-3-ones.2-烷氧基-1,4-戊二烯-3-酮的高效纳扎罗夫环化反应
Org Lett. 2003 Dec 25;5(26):4931-4. doi: 10.1021/ol036019z.
4
Asymmetric synthesis of multiple quaternary stereocentre-containing cyclopentyls by oxazolidinone-promoted Nazarov cyclizations.通过恶唑烷酮促进的纳扎罗夫环化反应不对称合成含多个季碳立体中心的环戊基化合物
Chem Sci. 2018 Apr 20;9(20):4644-4649. doi: 10.1039/c8sc00031j. eCollection 2018 May 28.
5
Total Synthesis of Farnesin through an Excited-State Nazarov Reaction.通过激发态 Nazarov 反应全合成法尼基丙酮。
Angew Chem Int Ed Engl. 2020 May 4;59(19):7444-7449. doi: 10.1002/anie.202001350. Epub 2020 Mar 17.
6
A catalytic asymmetric interrupted Nazarov-type cyclization of 2-indolylmethanols with cyclic enaminones.2-吲哚甲醇与环状烯胺酮的催化不对称中断 Nazarov 型环化反应。
Org Biomol Chem. 2018 Aug 1;16(30):5457-5464. doi: 10.1039/c8ob01427b.
7
Biomimetic 2-Imino-Nazarov Cyclizations via Eneallene Aziridination.通过烯丙基氮丙啶氮杂环丙烷化实现仿生 2-亚氨基-纳扎罗夫环化。
J Am Chem Soc. 2020 Mar 25;142(12):5568-5573. doi: 10.1021/jacs.0c02441. Epub 2020 Mar 10.
8
Asymmetric Nazarov Cyclizations of Unactivated Dienones by Hydrogen-Bond-Donor/Lewis Acid Co-Catalyzed, Enantioselective Proton-Transfer.通过氢键供体/路易斯酸共催化的对映选择性质子转移实现未活化二烯酮的不对称纳扎罗夫环化反应
Adv Synth Catal. 2020 Oct 6;362(19):4092-4097. doi: 10.1002/adsc.202000831. Epub 2020 Jul 26.
9
Enantioselective Nazarov Cyclizations Catalyzed by an Axial Chiral C F -Substituted Boron Lewis Acid.轴手性碳氟取代硼路易斯酸催化的对映选择性纳扎罗夫环化反应
Angew Chem Int Ed Engl. 2018 Aug 27;57(35):11441-11444. doi: 10.1002/anie.201806011. Epub 2018 Jul 26.
10
New Twists in Nazarov Cyclization Chemistry.Nazarov 环化反应化学的新进展。
Acc Chem Res. 2020 Sep 15;53(9):1822-1832. doi: 10.1021/acs.accounts.0c00284. Epub 2020 Aug 13.
引用本文的文献
1
Computational insights into the mechanisms and origins of switchable selectivity in gold(i)-catalyzed annulation of ynamides with isoxazoles 6π-electrocyclizations of azaheptatrienyl cations.金（I）催化异噁唑与烯酰胺环化反应中可切换选择性的机制及起源的计算洞察：氮杂庚三烯基阳离子的6π电环化反应
RSC Adv. 2023 Jun 14;13(26):18025-18037. doi: 10.1039/d3ra02839a. eCollection 2023 Jun 9.
2
Anion-accelerated asymmetric Nazarov cyclization: access to vicinal all-carbon quaternary stereocenters.阴离子加速不对称 Nazarov 环化反应：构建毗邻全碳季碳立体中心。
Org Biomol Chem. 2023 Jun 21;21(24):5014-5020. doi: 10.1039/d3ob00735a.
3
Catalytic aza-Nazarov cyclization reactions to access α-methylene-γ-lactam heterocycles.通过催化氮杂-Nazarov环化反应构建α-亚甲基-γ-内酰胺杂环。
Beilstein J Org Chem. 2023 Jan 17;19:66-77. doi: 10.3762/bjoc.19.6. eCollection 2023.
4
Asymmetric Gold(I)-Catalyzed Tandem Hydroarylation-Nazarov Cyclization: Enantioselective Access to Cyclopentenones.不对称金（I）催化的串联氢芳基化-纳扎罗夫环化反应：对环戊烯酮的对映选择性合成
Angew Chem Int Ed Engl. 2022 Aug 26;61(35):e202207406. doi: 10.1002/anie.202207406. Epub 2022 Jul 18.
5
Enyne diketones as substrate in asymmetric Nazarov cyclization for construction of chiral allene cyclopentenones.烯炔二酮作为不对称 Nazarov 环化反应的底物，用于构建手性烯丙基环戊烯酮。
Nat Commun. 2022 Jun 7;13(1):3146. doi: 10.1038/s41467-022-30846-y.
6
Concise Six-Step Asymmetric Approach to Ramelteon from an Acetophenone Derivative Using Ir, Rh, Cu, and Ni Catalysis.使用 Ir、Rh、Cu 和 Ni 催化，从苯乙酮衍生物出发，通过简洁的六步不对称方法制备雷美替胺。
J Org Chem. 2022 Feb 18;87(4):2129-2135. doi: 10.1021/acs.joc.1c01614. Epub 2021 Sep 30.
7
Bis-Cyclometalated Indazole and Benzimidazole Chiral-at-Iridium Complexes: Synthesis and Asymmetric Catalysis.双环金属化吲唑和苯并咪唑手性铱配合物的合成与不对称催化。
Molecules. 2021 Mar 24;26(7):1822. doi: 10.3390/molecules26071822.
8
Asymmetric Nazarov Cyclizations of Unactivated Dienones by Hydrogen-Bond-Donor/Lewis Acid Co-Catalyzed, Enantioselective Proton-Transfer.通过氢键供体/路易斯酸共催化的对映选择性质子转移实现未活化二烯酮的不对称纳扎罗夫环化反应
Adv Synth Catal. 2020 Oct 6;362(19):4092-4097. doi: 10.1002/adsc.202000831. Epub 2020 Jul 26.
9
Enantioselective PCCP Brønsted acid-catalyzed aza-Piancatelli rearrangement.对映选择性PCCP布朗斯特酸催化的氮杂皮安卡特利重排反应。
Beilstein J Org Chem. 2019 Jul 12;15:1569-1574. doi: 10.3762/bjoc.15.160. eCollection 2019.
10
Mechanistic Perspectives in the Regioselective Indole Addition to Unsymmetrical Silyloxyallyl Cations.区域选择性吲哚加成到不对称硅氧基烯丙基阳离子的机理研究。
J Org Chem. 2019 Jun 7;84(11):7166-7174. doi: 10.1021/acs.joc.9b00853. Epub 2019 May 16.
本文引用的文献
1
A reductive-coupling plus Nazarov cyclization sequence in the asymmetric synthesis of five-membered carbocycles.不对称合成五元碳环的还原偶联加 Nazarov 环化序列。
J Org Chem. 2010 Nov 5;75(21):7073-84. doi: 10.1021/jo100736p.
2
Brønsted acid-mediated Nazarov cyclization of vinylallenes.布朗斯特酸促进的乙烯基烯丙基环化反应。
J Org Chem. 2010 Aug 6;75(15):5410-3. doi: 10.1021/jo101112t.
3
An organocatalytic asymmetric Nazarov cyclization.有机催化不对称 Nazarov 环化反应。
J Am Chem Soc. 2010 Jun 23;132(24):8266-7. doi: 10.1021/ja103028r.
4
Asymmetric Nazarov reaction catalyzed by chiral tris(oxazoline)/copper(II).手性三（恶唑啉）/铜（II）催化的不对称纳扎罗夫反应。
Angew Chem Int Ed Engl. 2010 Jun 14;49(26):4463-6. doi: 10.1002/anie.200907266.
5
Organocatalytic asymmetric aza-Nazarov cyclization of an azirine.有机催化不对称氮杂-Nazarov 环化反应的氮杂环丙烷。
Chem Commun (Camb). 2010 Jun 7;46(21):3774-5. doi: 10.1039/b927564a. Epub 2010 Apr 28.
6
A novel approach to indoloditerpenes by Nazarov photocyclization: synthesis and biological investigations of terpendole E analogues.通过 Nazarov 光环化反应合成吲哚二萜类化合物的新方法：萜品烯 E 类似物的合成与生物学研究。
Org Lett. 2010 May 7;12(9):2096-9. doi: 10.1021/ol100579w.
7
Enamine-iminium ion Nazarov cyclization of alpha-ketoenones.Enamine-iminium 离子 Nazarov 环化反应的α-酮烯酮。
Org Lett. 2010 Feb 5;12(3):440-3. doi: 10.1021/ol9025765.
8
Chemical and biological studies of nakiterpiosin and nakiterpiosinone.纳克替泊辛和纳克替泊辛酮的化学和生物学研究。
J Am Chem Soc. 2010 Jan 13;132(1):371-83. doi: 10.1021/ja908626k.
9
Advances in the Nazarov cyclization.纳扎罗夫环化反应的进展
Curr Opin Drug Discov Devel. 2009 Nov;12(6):732-51.
10
Interrupting the Nazarov reaction: domino and cascade processes utilizing cyclopentenyl cations.阻断纳扎罗夫反应：利用环戊烯基阳离子的多米诺和级联反应。
Chem Commun (Camb). 2009 Oct 14(38):5676-88. doi: 10.1039/b908515g. Epub 2009 Aug 21.
Zotero 插件