低价铟作为酮和N-酰基腙烯丙基化反应的催化剂。
Low-valent indium as a catalyst for the allylation of ketones and N-acylhydrazones.
作者信息
Yoo Woo-Jin, Li Chao-Jun
机构信息
Department of Chemistry, McGill University, 801 Sherbrooke Street West, Montreal, Quebec, Canada.
出版信息
ChemSusChem. 2009;2(3):205-6. doi: 10.1002/cssc.200800243.
PMID:19212965
Abstract
Indium summer: The use of low-valent indium species in organic chemistry was, until quite recently, underdeveloped. Then came reports of indium(I) halides serving as excellent catalysts for the allylation of ketones and N-acylhydrazones with pinacol allylboronates, and more recently of indium(0) being used as a catalyst for the allylation of ketones in water.
摘要
铟之夏
直到最近，低价铟物种在有机化学中的应用仍未得到充分发展。随后有报道称，卤化铟（I）可作为酮和N-酰基腙与频哪醇烯丙基硼酸酯进行烯丙基化反应的优良催化剂，最近又有报道称铟（0）可作为水中酮烯丙基化反应的催化剂。
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