钯催化肉桂酸与芳基碘的脱羧交叉偶联反应。
Palladium-catalyzed decarboxylative cross-coupling reaction of cinnamic acid with aryl iodide.
作者信息
Wang Zhiyong, Ding Qiuping, He Xiaodan, Wu Jie
机构信息
Department of Chemistry, Fudan University, 220 Handan Road, Shanghai 200433, China.
出版信息
Org Biomol Chem. 2009 Mar 7;7(5):863-5. doi: 10.1039/b821870f. Epub 2009 Jan 14.
DOI:10.1039/b821870f
PMID:19225667
Abstract
A highly effective decarboxylative cross-coupling reaction of cinnamic acid with aryl iodide catalyzed by the combination of palladium chloride and CyJohnPhos in the presence of Ag2CO3 as an additive is described. The desired carbon-carbon bond formation proceeds efficiently with good functional-group tolerance.
摘要
描述了在碳酸银作为添加剂存在的情况下，氯化钯和CyJohnPhos组合催化肉桂酸与芳基碘发生的高效脱羧交叉偶联反应。所需的碳-碳键形成反应能高效进行，且具有良好的官能团耐受性。
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