纳米颗粒表面催化的分子间电子转移。
Intermolecular electron-transfer catalyzed on nanoparticle surfaces.
作者信息
Carver Adrienne M, De Mrinmoy, Bayraktar Halil, Rana Subinoy, Rotello Vincent M, Knapp Michael J
机构信息
Department of Chemistry, University of Massachusetts, Amherst, Massachusetts 01003, USA.
出版信息
J Am Chem Soc. 2009 Mar 25;131(11):3798-9. doi: 10.1021/ja806064t.
Abstract
Surface-functionalized nanoparticles enhance the rate of electron transfer (ET) between Cyt c(Fe(2+)) and Co(phen)(3)(3+) by a factor of 10(5) through simultaneous electrostatic binding of an ET donor and acceptor.
摘要
表面功能化纳米颗粒通过同时静电结合电子转移供体和受体，将细胞色素c（Fe(2+)）和三（邻菲罗啉）钴（Ⅲ）之间的电子转移（ET）速率提高了10^5倍。
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