Department of Molecular Engineering, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto 615-8510, Japan.
J Am Chem Soc. 2009 Mar 11;131(9):3198-200. doi: 10.1021/ja8096465.
A novel strategy for constructing a vertical arrangement of bicontinuous donor-acceptor arrays on a semiconducting electrode has been developed. The relationship between the film structure and the photoelectrochemical properties has been elucidated as a function of the number of donor layers for the first time. The maximum incident photon-to-current efficiency value (21%) is comparable to the highest value (20%) reported for vertical arrangements of bicontinuous donor-acceptor arrays on electrodes.
一种构建半导体电极上的双连续供体-受体排列的垂直排列的新策略已经被开发出来。首次阐明了薄膜结构与光电化学性质之间的关系，作为供体层数的函数。最大的光电子电流效率值（21%）可与电极上双连续供体-受体排列的垂直排列的最高值（20%）相媲美。
