Conti Enrico, Mackintosh Fred C
Division of Physics and Astronomy, Vrije Universiteit, 1081 HV Amsterdam, The Netherlands.
Phys Rev Lett. 2009 Feb 27;102(8):088102. doi: 10.1103/PhysRevLett.102.088102. Epub 2009 Feb 26.
Motivated by recent experiments showing that a variety of stiff biopolymer gels exhibit highly unusual negative normal elastic stresses, we simulate networks of elastic rods over a wide range of concentrations and bending stiffness. In all cases, we find that sheared networks develop significant negative normal stresses that coincide with other elastic nonlinearities, including shear stiffening and compressive bucking. The threshold strain for normal stress in these athermal networks increases with both concentration and stiffness, in contrast with prior predictions for thermal networks. This may provide an experimental test for entropic vs enthalpic effects in such networks.
受近期实验的启发,这些实验表明各种刚性生物聚合物凝胶表现出非常不寻常的负法向弹性应力,我们在很宽的浓度和弯曲刚度范围内模拟了弹性杆网络。在所有情况下,我们发现剪切后的网络会产生显著的负法向应力,这些应力与其他弹性非线性现象一致,包括剪切硬化和压缩屈曲。与之前对热网络的预测相反,这些无热网络中法向应力的阈值应变随浓度和刚度的增加而增加。这可能为此类网络中的熵效应与焓效应提供一个实验测试。