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包含金属作为结构单元的阴离子受体。

Anion receptors that contain metals as structural units.

作者信息

Amendola Valeria, Fabbrizzi Luigi

机构信息

Dipartimento di Chimica Generale, Università di Pavia, via Taramelli, 12, 27100, Pavia, Italy.

出版信息

Chem Commun (Camb). 2009 Feb 7(5):513-31. doi: 10.1039/b808264m. Epub 2008 Dec 3.

DOI:10.1039/b808264m
PMID:19283280
Abstract

Transition metals can be used as structural elements to build up anion receptors, enhancing H-bond donor tendencies, favouring the assembling of the molecular framework, inducing the formation of a cage. The versatile spectroscopic and electrochemical properties of the metal ion can provide a convenient signalling mechanism to communicate the occurrence of anion recognition.

摘要

过渡金属可用作构建阴离子受体的结构元素，增强氢键供体倾向，有利于分子框架的组装，诱导笼状结构的形成。金属离子多样的光谱和电化学性质可提供一种便捷的信号传导机制，以传达阴离子识别的发生情况。

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