联吡啶双脲基配体外部配位球中的分子内N-H···Cl氢键稳定了四面体FeLCl2配合物。
Intramolecular N-H···Cl hydrogen bonds in the outer coordination sphere of a bipyridyl bisurea-based ligand stabilize a tetrahedral FeLCl2 complex.
作者信息
Gavette Jesse V, Klug Christina M, Zakharov Lev N, Shores Matthew P, Haley Michael M, Johnson Darren W
机构信息
Department of Chemistry & Biochemistry and Materials Science Institute, University of Oregon, Eugene, OR 97403-1253, USA.
出版信息
Chem Commun (Camb). 2014 Jul 11;50(54):7173-5. doi: 10.1039/c4cc02297a.
Abstract
A bipyridyl-based anion receptor is utilized as a ligand in a tetrahedral FeCl2 complex and demonstrates secondary coordination sphere influence through intramolecular hydrogen bonding to the chloride ligands as evidenced by X-ray crystallography.
摘要
一种基于联吡啶的阴离子受体在四面体FeCl₂配合物中用作配体，并通过与氯配体的分子内氢键表现出二级配位球的影响，这一点通过X射线晶体学得到了证实。
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