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联吡啶双脲基配体外部配位球中的分子内N-H···Cl氢键稳定了四面体FeLCl2配合物。

Intramolecular N-H···Cl hydrogen bonds in the outer coordination sphere of a bipyridyl bisurea-based ligand stabilize a tetrahedral FeLCl2 complex.

作者信息

Gavette Jesse V, Klug Christina M, Zakharov Lev N, Shores Matthew P, Haley Michael M, Johnson Darren W

机构信息

Department of Chemistry & Biochemistry and Materials Science Institute, University of Oregon, Eugene, OR 97403-1253, USA.

出版信息

Chem Commun (Camb). 2014 Jul 11;50(54):7173-5. doi: 10.1039/c4cc02297a.

DOI:10.1039/c4cc02297a
PMID:24854889
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC4112994/
Abstract

A bipyridyl-based anion receptor is utilized as a ligand in a tetrahedral FeCl2 complex and demonstrates secondary coordination sphere influence through intramolecular hydrogen bonding to the chloride ligands as evidenced by X-ray crystallography.

摘要

一种基于联吡啶的阴离子受体在四面体FeCl₂配合物中用作配体，并通过与氯配体的分子内氢键表现出二级配位球的影响，这一点通过X射线晶体学得到了证实。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/421a/4157639/7b1104fc8d05/c4cc02297a-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/421a/4157639/051ffe0073f0/c4cc02297a-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/421a/4157639/b638565cb420/c4cc02297a-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/421a/4157639/7b1104fc8d05/c4cc02297a-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/421a/4157639/051ffe0073f0/c4cc02297a-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/421a/4157639/b638565cb420/c4cc02297a-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/421a/4157639/7b1104fc8d05/c4cc02297a-f3.jpg

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