通过铃木-宫浦交叉偶联设计用于正交官能化的硼试剂。
Devising boron reagents for orthogonal functionalization through Suzuki-Miyaura cross-coupling.
作者信息
Tobisu Mamoru, Chatani Naoto
机构信息
Frontier Research Base for Global Young Researchers, Graduate School of Engineering, Osaka University, Suita, Osaka 565-0871, Japan.
出版信息
Angew Chem Int Ed Engl. 2009;48(20):3565-8. doi: 10.1002/anie.200900465.
PMID:19309028
Abstract
Seeing the sites: The Suzuki-Miyaura reaction of substrates containing multiple coupling sites has been performed in a directed manner through the reactivity modulation of the boron moiety (see scheme). Several other strategies are also discussed.
摘要
考察反应位点
含多个偶联位点的底物的铃木-宫浦反应已通过硼部分的反应性调控以定向方式进行（见反应式）。还讨论了其他几种策略。
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