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一种基于前所未有的九核簇作为二级建筑单元的金属有机框架:结构与气体吸附行为

A metal-organic framework based on an unprecedented nonanuclear cluster as a secondary building unit: structure and gas sorption behavior.

作者信息

Park Mira, Moon Dohyun, Yoon Ji Woong, Chang Jong-San, Lah Myoung Soo

机构信息

Department of Chemistry and Applied Chemistry, Hanyang University, Ansan, Kyunggi-do, 426-791, Korea.

出版信息

Chem Commun (Camb). 2009 Apr 21(15):2026-8. doi: 10.1039/b818648k. Epub 2009 Feb 26.

DOI:10.1039/b818648k
PMID:19333479
Abstract

A 3D chiral microporous metal-organic framework containing a nonanuclear cluster as a secondary building unit was prepared using a bent and rigid dicarboxylic ligand, 2,7-naphthalene dicarboxylic acid, and the zinc ion, where a nonanuclear cluster with potential exposed metal sites is in the form of a corner-sharing cyclic trimer of a tetrahedral Zn(4)O motif.

摘要

使用弯曲且刚性的二羧酸配体2,7-萘二甲酸和锌离子制备了一种以九核簇作为二级建筑单元的三维手性微孔金属有机骨架,其中具有潜在暴露金属位点的九核簇呈四面体Zn(4)O基序的角共享环状三聚体形式。

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