Koso Shuichi, Furikado Ippei, Shimao Akira, Miyazawa Tomohisa, Kunimori Kimio, Tomishige Keiichi
Institute of Materials Science, University of Tsukuba, 1-1-1, Tennodai, Tsukuba, Ibaraki, 305-8573, Japan.
Chem Commun (Camb). 2009 Apr 21(15):2035-7. doi: 10.1039/b822942b. Epub 2009 Feb 26.
Direct conversion of tetrahydrofurfuryl alcohol, which is one of the biomass-derived chemicals, to 1,5-pentanediol was realized by chemoselective hydrogenolysis catalyzed by Rh/SiO(2) modified with ReO(x) species, and this reaction route gave higher yield than the conventional multi-step method.
通过用ReO(x)物种改性的Rh/SiO(2)催化的化学选择性氢解反应，实现了将生物质衍生化学品之一的四氢糠醇直接转化为1,5-戊二醇，并且该反应路线比传统的多步方法具有更高的产率。
