• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

有机微孔晶体对氮和氢的吸附

Nitrogen and hydrogen adsorption by an organic microporous crystal.

作者信息

Msayib Kadhum J, Book David, Budd Peter M, Chaukura Nhamo, Harris Kenneth D M, Helliwell Madeleine, Tedds Steven, Walton Allan, Warren John E, Xu Mingcan, McKeown Neil B

机构信息

School of Chemistry, Cardiff University, Cardiff CF10 AT, UK.

出版信息

Angew Chem Int Ed Engl. 2009;48(18):3273-7. doi: 10.1002/anie.200900234.

DOI:10.1002/anie.200900234
PMID:19343755
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3644174/
Abstract

Quick on the uptake: Following its identification during a targeted search, the intriguing crystal structure of 3,3',4,4'-tetra(trimethylsilylethynyl)biphenyl was investigated. Simple removal of the included solvent provides an organic crystal with an open microporous structure that has a striking similarity to that of zeolite A (see picture). Reversible adsorption of nitrogen and hydrogen gases at 77 K confirms that the microporosity is permanent.

摘要

反应迅速

在一次定向搜索中发现其结构后，对3,3',4,4'-四（三甲基硅乙炔基）联苯有趣的晶体结构进行了研究。简单地除去其中所含的溶剂，就得到了一种具有开放微孔结构的有机晶体，该结构与A型沸石的结构有着惊人的相似之处（见图）。在77 K下对氮气和氢气的可逆吸附证实了微孔的永久性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7834/3644174/9c78c13f359d/anie0048-3273-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7834/3644174/d032776bae29/anie0048-3273-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7834/3644174/9e5c7ecf2142/anie0048-3273-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7834/3644174/3e3561bd9913/anie0048-3273-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7834/3644174/deafb98d58f7/anie0048-3273-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7834/3644174/9c78c13f359d/anie0048-3273-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7834/3644174/d032776bae29/anie0048-3273-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7834/3644174/9e5c7ecf2142/anie0048-3273-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7834/3644174/3e3561bd9913/anie0048-3273-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7834/3644174/deafb98d58f7/anie0048-3273-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7834/3644174/9c78c13f359d/anie0048-3273-f5.jpg

相似文献

1
Nitrogen and hydrogen adsorption by an organic microporous crystal.有机微孔晶体对氮和氢的吸附
Angew Chem Int Ed Engl. 2009;48(18):3273-7. doi: 10.1002/anie.200900234.
2
Synthesis and gas adsorption properties of tetra-armed microporous organic polymer networks based on triphenylamine.基于三苯胺的四臂微孔有机聚合物网络的合成及其气体吸附性能。
Macromol Rapid Commun. 2014 Apr;35(8):834-9. doi: 10.1002/marc.201300864. Epub 2014 Feb 6.
3
Ordered microporous layered lanthanide 1,3,5-benzenetriphosphonates pillared with cationic organic molecules.有序微孔层状镧系1,3,5-苯三膦酸酯，由阳离子有机分子支撑。
Chemistry. 2015 Apr 13;21(16):6257-64. doi: 10.1002/chem.201406518. Epub 2015 Mar 9.
4
Planning Implications Related to Sterilization-Sensitive Science Investigations Associated with Mars Sample Return (MSR).与火星样本返回（MSR）相关的对灭菌敏感的科学研究的规划意义。
Astrobiology. 2022 Jun;22(S1):S112-S164. doi: 10.1089/AST.2021.0113. Epub 2022 May 19.
5
Rational Design of 7-Azaindole-Based Robust Microporous Hydrogen-Bonded Organic Framework for Gas Sorption.用于气体吸附的基于7-氮杂吲哚的坚固微孔氢键有机框架的合理设计
Angew Chem Int Ed Engl. 2025 Jan 2;64(1):e202412981. doi: 10.1002/anie.202412981. Epub 2024 Oct 18.
6
Efficient Removal of Volatile Organic Compounds by FAU-Type Zeolite Coatings.FAU 型沸石涂层对挥发性有机化合物的高效去除。
Molecules. 2020 Jul 23;25(15):3336. doi: 10.3390/molecules25153336.
7
Microporous water with high gas solubilities.具有高气体溶解度的微孔水。
Nature. 2022 Aug;608(7924):712-718. doi: 10.1038/s41586-022-05029-w. Epub 2022 Aug 24.
8
Zeolite-templated microporous carbon as a superior adsorbent for removal of monoaromatic compounds from aqueous solution.沸石模板微孔碳作为一种从水溶液中去除单芳烃化合物的优良吸附剂。
Environ Sci Technol. 2009 Oct 15;43(20):7870-6. doi: 10.1021/es901497w.
9
BILP-19-An Ultramicroporous Organic Network with Exceptional Carbon Dioxide Uptake.BILP-19-一种具有优异二氧化碳吸附性能的超微孔有机网络。
Molecules. 2017 Aug 12;22(8):1343. doi: 10.3390/molecules22081343.
10
A zirconium metal-organic framework with an exceptionally high volumetric surface area.一种具有极高体积表面积的锆基金属有机框架材料。
Dalton Trans. 2017 Oct 24;46(41):14270-14276. doi: 10.1039/c7dt03394j.

引用本文的文献

1
Discovery of a molecular adsorbent for efficient CO/CH separation using a computation-ready experimental database of porous molecular materials.利用多孔分子材料的可用于计算的实验数据库发现一种用于高效CO/CH分离的分子吸附剂。
Chem Sci. 2025 Apr 8;16(18):7685-7694. doi: 10.1039/d5sc01532d. eCollection 2025 May 7.
2
A van der Waals porous crystal featuring conformational flexibility and permanent porosity for ultrafast water release.一种具有构象灵活性和永久孔隙率以实现超快水释放的范德华多孔晶体。
Commun Chem. 2024 Nov 30;7(1):282. doi: 10.1038/s42004-024-01366-1.
3
Relationship between spatially heterogeneous reaction dynamics and photochemical kinetics in single crystals of anthracene derivatives.

本文引用的文献

1
Methane, carbon dioxide and hydrogen storage in nanoporous dipeptide-based materials.纳米多孔二肽基材料中甲烷、二氧化碳和氢气的储存
Chem Commun (Camb). 2009 Jan 21(3):284-6. doi: 10.1039/b820200a. Epub 2008 Dec 4.
2
Gas storage in nanoporous materials.纳米多孔材料中的气体储存
Angew Chem Int Ed Engl. 2008;47(27):4966-81. doi: 10.1002/anie.200703934.
3
Clathrate formation from octaazaphthalocyanines possessing bulky phenoxyl substituents: a new cubic crystal containing solvent-filled, nanoscale voids.
蒽衍生物单晶中空间非均相反应动力学与光化学动力学之间的关系。
Chem Sci. 2024 Jul 26;15(33):13421-13428. doi: 10.1039/d4sc03060e. eCollection 2024 Aug 22.
4
Facile fabrication of recyclable robust noncovalent porous crystals from low-symmetry helicene derivative.通过低对称六螺烯衍生物轻松制备可回收的坚固非共价多孔晶体。
Nat Commun. 2024 Jun 27;15(1):5469. doi: 10.1038/s41467-024-49865-y.
5
Degradation of Bisphenol A by Nitrogen-Rich ZIF-8-Derived Carbon Materials-Activated Peroxymonosulfate.富氮ZIF-8衍生碳材料活化过一硫酸盐降解双酚A
Toxics. 2024 May 12;12(5):359. doi: 10.3390/toxics12050359.
6
Porous and Close Packed Supramolecular Assemblies from 2,4-Difluoronitrobenzene with Three Different Linkers and an -Butylamine Cap.由2,4-二氟硝基苯与三种不同连接体及正丁胺封端剂形成的多孔和密堆积超分子组装体。
Int J Mol Sci. 2023 Sep 28;24(19):14683. doi: 10.3390/ijms241914683.
7
Sigmoidally hydrochromic molecular porous crystal with rotatable dendrons.具有可旋转树枝状结构的S形水致变色分子多孔晶体。
Commun Chem. 2020 Aug 17;3(1):118. doi: 10.1038/s42004-020-00364-3.
8
Solvophobicity-directed assembly of microporous molecular crystals.微孔分子晶体的疏溶剂导向组装
Commun Chem. 2021 Aug 20;4(1):122. doi: 10.1038/s42004-021-00561-8.
9
Identifying porous cage subsets in the Cambridge Structural Database using topological data analysis.使用拓扑数据分析在剑桥结构数据库中识别多孔笼状子集。
Chem Sci. 2022 Oct 31;13(45):13507-13523. doi: 10.1039/d2sc03171j. eCollection 2022 Nov 23.
10
Energy-Efficient Iodine Uptake by a Molecular Host⋅Guest Crystal.分子主客体晶体的高效碘吸收
Angew Chem Int Ed Engl. 2022 Dec 5;61(49):e202214039. doi: 10.1002/anie.202214039. Epub 2022 Oct 26.
Chemistry. 2008;14(16):4810-5. doi: 10.1002/chem.200701980.
4
Cucurbit[6]uril: organic molecular porous material with permanent porosity, exceptional stability, and acetylene sorption properties.
Angew Chem Int Ed Engl. 2008;47(18):3352-5. doi: 10.1002/anie.200800772.
5
Hybrid porous solids: past, present, future.混合多孔固体：过去、现在与未来。
Chem Soc Rev. 2008 Jan;37(1):191-214. doi: 10.1039/b618320b. Epub 2007 Sep 19.
6
A quadruply stranded metallohelicate and its spontaneous dimerization into an interlocked metallohelicate.一种四重链金属螺旋体及其自发二聚形成互锁金属螺旋体。
Angew Chem Int Ed Engl. 2008;47(4):706-10. doi: 10.1002/anie.200703162.
7
Profiting from nature: macroporous copper with superior mechanical properties.
Chem Commun (Camb). 2007 Sep 14(34):3547-9. doi: 10.1039/b707469g.
8
Designed synthesis of 3D covalent organic frameworks.三维共价有机框架的设计合成
Science. 2007 Apr 13;316(5822):268-72. doi: 10.1126/science.1139915.
9
The potential of organic polymer-based hydrogen storage materials.基于有机聚合物的储氢材料的潜力。
Phys Chem Chem Phys. 2007 Apr 21;9(15):1802-8. doi: 10.1039/b618053a. Epub 2007 Feb 16.
10
Engineering void space in organic van der Waals crystals: calixarenes lead the way.在有机范德华晶体中构建空隙空间：杯芳烃引领潮流。
Chem Soc Rev. 2007 Feb;36(2):236-45. doi: 10.1039/b606047c. Epub 2007 Jan 2.