Megiatto Jackson D, Schuster David I
Chemistry Department, New York University, 100, Washington Square East, room 1001, New York, NY 10003, USA.
Chemistry. 2009;15(22):5444-8. doi: 10.1002/chem.200900536.
"Double Click" and it's locked: Copper(I)-templated synthesis in conjunction with "click" chemistry has been applied in a straightforward manner for the preparation of functionalized [3]catenanes. This methodology allows the construction of higher interlocked architectures, including polymers and networks as well as electron donor-acceptor nanomaterials suitable for investigation of long-range photoinduced electron-transfer processes.
“双击”及其受限:铜(I)模板合成与“点击”化学相结合已被直接应用于制备功能化的[3]连环烷。这种方法能够构建更高级的互锁结构,包括聚合物、网络以及适用于研究长程光致电子转移过程的电子供体-受体纳米材料。