基于 Cu(I)-菲咯啉的索烃和轮烷的替代脱金属方法。
Alternative demetalation method for Cu(I)-phenanthroline-based catenanes and rotaxanes.
机构信息
Chemistry Department, New York University, New York City, New York 10003, United States.
出版信息
Org Lett. 2011 Apr 1;13(7):1808-11. doi: 10.1021/ol200304d. Epub 2011 Mar 8.
Abstract
A new and less hazardous procedure for demetalation of Cu(I)-phenanthroline-based interlocked molecules, using aqueous NH(4)OH rather than toxic KCN, has been developed. The conditions are compatible with materials containing nucleophile-sensitive appended groups such as C(60), and coordinating moieties such as zinc(II)-porphyrins.
摘要
已经开发出一种新的、危险性更小的脱金属方法，用于基于 Cu(I)-菲咯啉的互锁分子，使用的是无毒的 NH(4)OH 而不是有毒的 KCN。这些条件与含有亲核试剂敏感附加基团（如 C(60)）和配位部分（如锌(II)-卟啉）的材料兼容。
相似文献
1
Alternative demetalation method for Cu(I)-phenanthroline-based catenanes and rotaxanes.基于 Cu(I)-菲咯啉的索烃和轮烷的替代脱金属方法。
Org Lett. 2011 Apr 1;13(7):1808-11. doi: 10.1021/ol200304d. Epub 2011 Mar 8.
2
Synthesis of rotacatenanes by the combination of Cu-mediated threading reaction and the template method: the dual role of one ligand.通过 Cu 介导的套索反应和模板法的结合合成轮状轮烷：一种配体的双重作用。
Chem Commun (Camb). 2014 Jan 7;50(2):204-6. doi: 10.1039/c3cc47425a.
3
Construction of photoswitchable rotaxanes and catenanes containing dithienylethene fragments.含二噻吩乙烯片段的光开关轮烷和索烃的构建。
Org Biomol Chem. 2015 Jul 14;13(26):7313-22. doi: 10.1039/c5ob00864f. Epub 2015 Jun 10.
4
Ground-state kinetics of bistable redox-active donor-acceptor mechanically interlocked molecules.双稳态氧化还原活性给体-受体机械互锁分子的基态动力学。
Acc Chem Res. 2014 Feb 18;47(2):482-93. doi: 10.1021/ar400161z. Epub 2013 Dec 16.
5
Polypseudorotaxanes via ring-opening metathesis polymerizations of [2]catenanes.通过[2]连环烷的开环易位聚合制备的聚准轮烷
J Am Chem Soc. 2008 Nov 19;130(46):15246-7. doi: 10.1021/ja806122r. Epub 2008 Oct 22.
6
Self-assembly of [3]catenanes and a [4]molecular necklace based on a cryptand/paraquat recognition motif.基于穴醚/百草枯识别基序的[3]索烃和[4]分子项链的自组装。
Org Lett. 2015 Jun 5;17(11):2804-7. doi: 10.1021/acs.orglett.5b01211. Epub 2015 May 21.
7
Synthesis of large [2]rotaxanes. The relationship between the size of the blocking group and the stability of the rotaxane.大环[2]轮烷的合成。封端基团的大小与轮烷稳定性的关系。
J Org Chem. 2013 Apr 19;78(8):3553-60. doi: 10.1021/jo302800t. Epub 2013 Apr 11.
8
Synthesis of [3]rotaxanes that utilize the catalytic activity of a macrocyclic phenanthroline-Cu Complex: remarkable effect of the length of the axle precursor.利用大环菲咯啉 - 铜配合物的催化活性合成[3]轮烷：轴前体长度的显著影响。
Chemistry. 2015 Jan 26;21(5):2139-45. doi: 10.1002/chem.201405090. Epub 2014 Dec 2.
9
Hydrogen bond templated synthesis of catenanes and rotaxanes from a single isophthalic acid derivative.基于单一间苯二甲酸衍生物通过氢键模板法合成索烃和轮烷。
Org Biomol Chem. 2023 Jan 4;21(2):402-414. doi: 10.1039/d2ob02019j.
10
Synthesizing [2]Rotaxanes and [2]Catenanes through Na(+)-Templated Clipping of Macrocycles around Oligo(ethylene glycol) Units.通过 Na(+)-模板化夹在聚（乙二醇）单元周围大环来合成[2]轮烷和[2]索烃。
Org Lett. 2015 May 1;17(9):2158-61. doi: 10.1021/acs.orglett.5b00748. Epub 2015 Apr 23.
引用本文的文献
1
Conducting Copper(I/II)-Metallopolymer for the Electrocatalytic Oxygen Reduction Reaction (ORR) with High Kinetic Current Density.用于具有高动力学电流密度的电催化氧还原反应（ORR）的导电铜（I/II）金属聚合物
Polymers (Basel). 2018 Sep 7;10(9):1002. doi: 10.3390/polym10091002.
2
Multistep energy and electron transfer processes in novel rotaxane donor-acceptor hybrids generating microsecond-lived charge separated states.新型轮烷供体-受体杂化物中产生微秒级寿命电荷分离态的多步能量和电子转移过程。
Chem Sci. 2015 Dec 1;6(12):7293-7304. doi: 10.1039/c5sc02895g. Epub 2015 Oct 2.
3
Porphyrin-Polyyne [3]- and [5]Rotaxanes.卟啉-聚炔[3]-和[5]轮烷。
Org Lett. 2017 Jan 20;19(2):348-351. doi: 10.1021/acs.orglett.6b03528. Epub 2017 Jan 5.
4
Topological and Conformational Effects on Electron Transfer Dynamics in Porphyrin-[60]Fullerene Interlocked Systems.卟啉 - [60]富勒烯互锁体系中电子转移动力学的拓扑和构象效应
Chem Mater. 2012 Jul 10;24(13):2472-2485. doi: 10.1021/cm3004408. Epub 2012 Jun 18.
本文引用的文献
1
Convergent synthesis and photoinduced processes in multi-chromophoric rotaxanes.多发色轮烷中的汇聚合成和光诱导过程。
J Phys Chem B. 2010 Nov 18;114(45):14408-19. doi: 10.1021/jp101154k. Epub 2010 Jun 2.
2
[2]Catenanes decorated with porphyrin and [60]fullerene groups: design, convergent synthesis, and photoinduced processes.[2] 卟啉和 [60] 富勒烯基团修饰的轮烷：设计、收敛合成和光诱导过程。
J Am Chem Soc. 2010 Mar 24;132(11):3847-61. doi: 10.1021/ja910149f.
3
Bilability is defined when one electron is used to switch between concerted and stepwise pathways in Cu(I)-based bistable [2/3]pseudorotaxanes.当一个电子用于在基于 Cu(I)的双稳态 [2/3]假轮烷中协同和逐步途径之间切换时，就定义了电子的可翻转性。
J Am Chem Soc. 2010 Feb 10;132(5):1665-75. doi: 10.1021/ja908877d.
4
Efficient one-pot synthesis of rotaxanes bearing electron donors and [60]fullerene.带电子给体和 [60]富勒烯的轮烷的高效一锅合成。
Org Lett. 2009 Sep 17;11(18):4152-5. doi: 10.1021/ol9016645.
5
"Click" methodology for synthesis of functionalized [3]catenanes: toward higher interlocked structures.用于合成功能化[3]连环烷的“点击”方法：迈向更高的互锁结构
Chemistry. 2009;15(22):5444-8. doi: 10.1002/chem.200900536.
6
Design and synthesis of porphyrin-containing catenanes and rotaxanes.含卟啉的索烃和轮烷的设计与合成。
Chem Soc Rev. 2009 Feb;38(2):422-42. doi: 10.1039/b710908n. Epub 2008 Nov 24.
7
Synthesis of [2]catenanes by oxidative intramolecular diyne coupling mediated by macrocyclic copper(I) complexes.通过大环铜（I）配合物介导的氧化分子内二炔偶联合成[2]连环烷。
Angew Chem Int Ed Engl. 2009;48(3):504-7. doi: 10.1002/anie.200804864.
8
Polypseudorotaxanes via ring-opening metathesis polymerizations of [2]catenanes.通过[2]连环烷的开环易位聚合制备的聚准轮烷
J Am Chem Soc. 2008 Nov 19;130(46):15246-7. doi: 10.1021/ja806122r. Epub 2008 Oct 22.
9
General method for synthesis of functionalized macrocycles and catenanes utilizing "click" chemistry.利用“点击”化学合成功能化大环化合物和索烃的通用方法。
J Am Chem Soc. 2008 Oct 1;130(39):12872-3. doi: 10.1021/ja8050519. Epub 2008 Sep 4.
10
Convergent synthesis and photophysics of [60]fullerene/porphyrin-based rotaxanes.基于[60]富勒烯/卟啉的轮烷的汇聚合成与光物理性质
J Am Chem Soc. 2004 Mar 24;126(11):3388-9. doi: 10.1021/ja039698h.
Zotero 插件