溴化亚铜催化叔胺与二氟烯醇硅醚的氧化二氟甲基化反应。
CuBr-catalyzed oxidative difluoromethylation of tertiary amines with difluoroenol silyl ethers.
作者信息
Chu Lingling, Zhang Xingang, Qing Feng-Ling
机构信息
Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032, China.
出版信息
Org Lett. 2009 May 21;11(10):2197-200. doi: 10.1021/ol900541n.
PMID:19378964
Abstract
CuBr-catalyzed oxidative difluoromethylation of readily available tertiary amines with difluoroenol silyl ethers was performed under mild conditions to afford beta-amine-alpha,alpha-difluoro ketones.
摘要
在温和条件下，用二氟烯醇硅醚对易得的叔胺进行溴化亚铜催化的氧化二氟甲基化反应，以得到β-胺-α,α-二氟酮。
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