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一种通过相互穿插由二维薄片构建而成的具有动态特征的三维多孔金属有机框架。

A three-dimensional porous metal-organic framework constructed from two-dimensional sheets via interdigitation exhibiting dynamic features.

作者信息

Ma Shengqian, Sun Daofeng, Forster Paul M, Yuan Daqiang, Zhuang Wenjuan, Chen Yu-Sheng, Parise John B, Zhou Hong-Cai

机构信息

Chemical Sciences and Engineering Division, Argonne National Laboratory, 9700 S. Cass Avenue, Argonne, Illinois 60439, USA.

出版信息

Inorg Chem. 2009 Jun 1;48(11):4616-8. doi: 10.1021/ic900372t.

DOI:10.1021/ic900372t
PMID:19388643
Abstract

A three-dimensional porous metal-organic framework (PCN-18) was constructed through interdigitating two-dimensional grid sheets composed of 4,4'-(anthracene-9,10-diyl)dibenzoate and copper paddlewheel secondary building units, and its dynamic features were evidenced by gas sorption isotherms.

摘要

通过将由4,4'-(蒽-9,10-二基)二苯甲酸酯和铜桨轮二级构筑单元组成的二维网格片相互交叉,构建了一种三维多孔金属有机框架(PCN-18),其动态特性通过气体吸附等温线得到了证实。

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