Ma Shengqian, Sun Daofeng, Forster Paul M, Yuan Daqiang, Zhuang Wenjuan, Chen Yu-Sheng, Parise John B, Zhou Hong-Cai
Chemical Sciences and Engineering Division, Argonne National Laboratory, 9700 S. Cass Avenue, Argonne, Illinois 60439, USA.
Inorg Chem. 2009 Jun 1;48(11):4616-8. doi: 10.1021/ic900372t.
A three-dimensional porous metal-organic framework (PCN-18) was constructed through interdigitating two-dimensional grid sheets composed of 4,4'-(anthracene-9,10-diyl)dibenzoate and copper paddlewheel secondary building units, and its dynamic features were evidenced by gas sorption isotherms.
通过将由4,4'-(蒽-9,10-二基)二苯甲酸酯和铜桨轮二级构筑单元组成的二维网格片相互交叉,构建了一种三维多孔金属有机框架(PCN-18),其动态特性通过气体吸附等温线得到了证实。