Xu Dan, Liu Zhaoping, Yang Hongzhou, Liu Qingsheng, Zhang Jun, Fang Jiye, Zou Shouzhong, Sun Kai
Department of Chemistry, State University of New York at Binghamton, Binghamton, NY 13902, USA.
Angew Chem Int Ed Engl. 2009;48(23):4217-21. doi: 10.1002/anie.200900293.
Shape-controlled catalysis: High-quality Pt-Cu nanocubes with an average size of about 8 nm (see picture, scale bar = 20 nm) were synthesized from a high-temperature organic solution system in the presence of various capping ligands. These cubic Pt-Cu nanocrystals terminated with {100} facets demonstrated a superior catalytic activity towards methanol oxidation compared to similar sized Pt-Cu and Pt nanospheres.
在各种封端配体存在的情况下，从高温有机溶液体系中合成了平均尺寸约为8nm的高质量Pt-Cu纳米立方体（见图，比例尺 = 20nm）。与类似尺寸的Pt-Cu和Pt纳米球相比，这些以{100}面为终端的立方Pt-Cu纳米晶体对甲醇氧化表现出优异的催化活性。
