混合价卟啉π-阳离子自由基衍生物：电化学研究
Mixed-Valence Porphyrin π-Cation Radical Derivatives: Electrochemical Investigations.
作者信息
Scheidt W Robert, Buentello Kristin E, Ehlinger Noelle, Cinquantini Arnaldo, Fontani Marco, Laschi Franco
机构信息
The Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, Indiana 46556.
出版信息
Inorganica Chim Acta. 2008 May 5;361(6):1722-1727. doi: 10.1016/j.ica.2006.12.028.
Abstract
The electrochemistry of [Cu(OEP)] and [Ni(OEP)] are compared with the mixed-valence π-cations [Cu(OEP•/2)]2+and[Ni(OEP•/2)]2+. These electrochemical studies, carried out with cyclic voltametry and hydrodynamic voltametry, show that the mixed valence π-cations have distinct electrochemical properties, although the differences between the M(OEP) and [M(OEP•/2)]2+/0 processes are subtle.
摘要
将[Cu(OEP)]和[Ni(OEP)]的电化学性质与混合价态π阳离子[Cu(OEP•/2)]2+和[Ni(OEP•/2)]2+进行了比较。这些采用循环伏安法和流体动力学伏安法进行的电化学研究表明，尽管M(OEP)和[M(OEP•/2)]2+/0过程之间的差异很细微，但混合价态π阳离子具有独特的电化学性质。
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