Wang H Y, Yang Y, Wang Y, Zhao Y Y, Li X, Wang C
Alan G. MacDiarmid Institute, Jilin University, Changchun, 130012, P. R. China.
J Nanosci Nanotechnol. 2009 Feb;9(2):1522-5. doi: 10.1166/jnn.2009.c193.
Luminescent rare-earth oxyfluoride nanofibers were first prepared used electrospinning technique in this paper. The formation of rare-earth oxyfluoride nanofibers was carried out by calcining rare-earth trifluoroacetic acid/Poly(vinyl pyrrolidone) [R (CF3CO2)3/PVP (R = Eu, Ho)] nanofibers, which were electrospun from the mixture solution of R (CF3CO2)3 and PVP. Scanning electron microscopy (SEM), transmission electron microscopy (TEM), and X-ray diffraction (XRD) analyses demonstrated the morphology of the Rare-Earth Oxyfluoride (ROF) nanofibers, thestructure and the cubic crystal in ROF fibers. The characteristic photoluminescence from ROF nanofibers were observed with laser excitation at 290 nm.
本文首次采用静电纺丝技术制备了发光稀土氟氧化物纳米纤维。通过煅烧由稀土三氟乙酸/聚乙烯吡咯烷酮[R(CF3CO2)3/PVP(R = Eu, Ho)]纳米纤维形成稀土氟氧化物纳米纤维,其中R(CF3CO2)3/PVP纳米纤维是由R(CF3CO2)3和PVP的混合溶液静电纺丝而成。扫描电子显微镜(SEM)、透射电子显微镜(TEM)和X射线衍射(XRD)分析证实了稀土氟氧化物(ROF)纳米纤维的形态、结构以及ROF纤维中的立方晶体。在290nm激光激发下观察到了ROF纳米纤维的特征光致发光。