Zhang Zexin, Xu Ning, Chen Daniel T N, Yunker Peter, Alsayed Ahmed M, Aptowicz Kevin B, Habdas Piotr, Liu Andrea J, Nagel Sidney R, Yodh Arjun G
Department of Physics and Astronomy, University of Pennsylvania, Philadelphia, Pennsylvania 19104, USA.
Nature. 2009 May 14;459(7244):230-3. doi: 10.1038/nature07998.
When the packing fraction is increased sufficiently, loose particulates jam to form a rigid solid in which the constituents are no longer free to move. In typical granular materials and foams, the thermal energy is too small to produce structural rearrangements. In this zero-temperature (T = 0) limit, multiple diverging and vanishing length scales characterize the approach to a sharp jamming transition. However, because thermal motion becomes relevant when the particles are small enough, it is imperative to understand how these length scales evolve as the temperature is increased. Here we used both colloidal experiments and computer simulations to progress beyond the zero-temperature limit to track one of the key parameters-the overlap distance between neighbouring particles-which vanishes at the T = 0 jamming transition. We find that this structural feature retains a vestige of its T = 0 behaviour and evolves in an unusual manner, which has masked its appearance until now. It is evident as a function of packing fraction at fixed temperature, but not as a function of temperature at fixed packing fraction or pressure. Our results conclusively demonstrate that length scales associated with the T = 0 jamming transition persist in thermal systems, not only in simulations but also in laboratory experiments.
当堆积分数充分增加时,松散的颗粒会相互卡住,形成一种刚性固体,其中的组分不再能够自由移动。在典型的颗粒材料和泡沫中,热能太小,无法产生结构重排。在这个零温度(T = 0)极限下,多个发散和消失的长度尺度表征了向尖锐堵塞转变的过程。然而,由于当颗粒足够小时热运动变得重要,所以必须了解这些长度尺度如何随着温度升高而演变。在这里,我们通过胶体实验和计算机模拟,超越了零温度极限,以追踪一个关键参数——相邻颗粒之间的重叠距离,该参数在T = 0堵塞转变时消失。我们发现,这一结构特征保留了其T = 0时行为的痕迹,并以一种不寻常的方式演变,这使得它的出现至今一直被掩盖。它在固定温度下是堆积分数的函数,但在固定堆积分数或压力下不是温度的函数。我们的结果确凿地表明,与T = 0堵塞转变相关的长度尺度在热系统中持续存在,不仅在模拟中如此,在实验室实验中也是如此。