铜催化芳基氯化物、溴化物和碘化物与氨水的高效偶联反应。
Efficient copper-catalyzed coupling of aryl chlorides, bromides and iodides with aqueous ammonia.
作者信息
Xu Hanhui, Wolf Christian
机构信息
Department of Chemistry, Georgetown University, Washington, DC 20057, USA.
出版信息
Chem Commun (Camb). 2009 Jun 7(21):3035-7. doi: 10.1039/b904188e. Epub 2009 Apr 27.
DOI:10.1039/b904188e
PMID:19462078
Abstract
The copper(I)-catalyzed synthesis of a range of primary anilines from electron-rich and electron-deficient aryl halides including aryl chlorides has been achieved with aqueous ammonia, avoiding the need for inert atmosphere, expensive catalysts and ligands, anhydrous solvents, and additional base or other additives.
摘要
利用氨水已实现了铜（I）催化一系列富电子和缺电子芳基卤化物（包括芳基氯化物）合成伯苯胺，无需惰性气氛、昂贵的催化剂和配体、无水溶剂以及额外的碱或其他添加剂。
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