用于制备作为模块化化学构建块的π共轭连接子的方便方法。
Convenient methods for preparing pi-conjugated linkers as building blocks for modular chemistry.
机构信息
Institute of Organic Chemistry and Technology, Faculty of Chemical Technology, University of Pardubice, nám Cs. legií 565, Pardubice, 532 10, Czech Republic.
出版信息
Beilstein J Org Chem. 2009 Apr 14;5:11. doi: 10.3762/bjoc.5.11.
Simple, straightforward and optimized procedures for preparing extended pi-conjugated linkers are described. Either unsubstituted or 4-donor substituted pi-linkers bearing a styryl, biphenyl, phenylethenylphenyl, and phenylethynylphenyl pi-conjugated backbone are functionalized with boronic pinacol esters as well as with terminal acetylene moieties allowing their further use as building blocks in Suzuki-Miyaura or Sonogashira coupling reactions.
描述了制备扩展的π共轭连接体的简单、直接和优化的方法。带有苯乙烯基、联苯基、苯乙炔基苯基和苯乙炔基苯基π共轭主链的未取代或 4-供体取代的π-连接体可以用硼酸频哪醇酯以及末端炔基官能化，这使得它们可以进一步用作 Suzuki-Miyaura 或 Sonogashira 偶联反应的构建块。
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