Majetich George, Grove Jeremy L
Department of Chemistry, University of Georgia, Athens, Georgia 30602, USA.
Org Lett. 2009 Jul 2;11(13):2904-7. doi: 10.1021/ol9009128.
The first asymmetric total syntheses of 19-deoxyicetexone, icetexone, and 5-epi-icetexone was achieved from epimeric tricyclic dienes.
从差向异构的三环二烯出发,首次实现了19-脱氧异西酮、异西酮和5-表异西酮的不对称全合成。