（±）-阿帕里辛的首次全合成。
The first total synthesis of (+/-)-apparicine.
作者信息
Bennasar M-Lluïsa, Zulaica Ester, Solé Daniel, Alonso Sandra
机构信息
Laboratory of Organic Chemistry, Faculty of Pharmacy and Institut de Biomedicina (IBUB), University of Barcelona, Barcelona 08028, Spain.
出版信息
Chem Commun (Camb). 2009 Jun 21(23):3372-4. doi: 10.1039/b903577j. Epub 2009 Apr 27.
DOI:10.1039/b903577j
PMID:19503874
Abstract
The first total synthesis of the indole alkaloid apparicine has been developed through a sequence that includes an indole-templated ring-closing metathesis and a vinyl halide Heck cyclization.
摘要
通过包括吲哚模板的闭环复分解反应和卤化乙烯基Heck环化反应的一系列反应，首次实现了吲哚生物碱阿帕西汀的全合成。
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