Dang Li, Lin Zhenyang, Marder Todd B
Department of Chemistry, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong.
Chem Commun (Camb). 2009 Jul 21(27):3987-95. doi: 10.1039/b903098k. Epub 2009 May 18.
In this feature article, we discuss selected recent aspects of metal boryl (M-BR2) chemistry pertaining, in particular, to the role of late and post-transition metal boryl complexes in various catalytic processes. The exceptionally strong sigma-donor properties of boryl ligands and their related nucleophilic behaviour are highlighted.
在这篇专题文章中，我们讨论了金属硼基（M-BR₂）化学最近的一些特定方面，尤其涉及后过渡金属硼基配合物在各种催化过程中的作用。文中强调了硼基配体异常强的σ供体性质及其相关的亲核行为。
