Department of Chemistry and the Molecular Structure Center, Indiana University, Bloomington, IN 46405, USA.
Dalton Trans. 2010 Jan 14(2):358-60. doi: 10.1039/b912040h. Epub 2009 Sep 8.
Mononuclear nickel and cobalt boryl complexes have been prepared via sigma-bond metathesis reactions and in the case of nickel, an intermediate comprised of a Lewis acid-base type adduct has been experimentally detected by (31)P NMR spectroscopy and its structure probed by DFT calculations.
单核镍和钴硼基配合物是通过 sigma 键复分解反应制备的，而镍的情况则通过 (31)P NMR 光谱实验检测到了由路易斯酸碱型加合物组成的中间体，并通过 DFT 计算探测了其结构。
