Ji Ke-Gong, Shu Xing-Zhong, Zhao Shu-Chun, Zhu Hai-Tao, Niu Yan-Ning, Liu Xue-Yuan, Liang Yong-Min
State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, PR China.
Org Lett. 2009 Aug 6;11(15):3206-9. doi: 10.1021/ol901270b.
A mild and direct process for C-C bond formation from propargylic alcohols and olefin has been developed in the presence of a silver catalyst. In this reaction, trace amounts of water were necessary and allene alcohols 2 and 1,3-dienes 3 were obtained selectively.
在银催化剂存在下,已开发出一种由炔丙醇和烯烃形成碳 - 碳键的温和且直接的方法。在该反应中,需要痕量的水,并且可选择性地获得烯丙醇2和1,3 - 二烯3。